TY  - JOUR
AU  - Leka, ZB
AU  - Leovac, Vukadin M.
AU  - Lukic, S
AU  - Sabo, Tibor
AU  - Trifunović, Srećko R.
AU  - Szecsenyi, KM
PY  - 2006
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/773
AB  - Triammonium-N-dithiocarboxyiminodiacetate, (NH4)(3)L, a new dithiocarbamato derivative of iminodiacetate, has been synthesized. The coordination properties of the ligand were tested in reactions with copper(II), nickel(II) and palladium(II) salts in acidic solutions. Complexes with a general formula M(H2L)(2) were obtained, with the coordination taking place through the sulfur atoms of the dithiocarbamate moiety. The new compounds were characterized by elemental analysis, UV/VIS and IR spectroscopy, thermal analysis and magnetic measurements. In addition, the ligand was characterized by H-1- and C-13-NMR spectroscopy and molar conductivity measurements. The copper(II) complex is paramagnetic, while the nickel(II) and palladium(II) compounds are diamagnetic. The thermal decomposition of all compounds is continuous and the thermal stability of the complexes is higher than that of the ligand, as expected.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Synthesis and physico-chemical characterization of new dithiocarabamato ligand and its complexes with copper(II), nickel(II) and palladium(II)
VL  - 83
IS  - 3
SP  - 687
EP  - 691
DO  - 10.1007/s10973-005-6938-7
ER  - 

@article{
author = "Leka, ZB and Leovac, Vukadin M. and Lukic, S and Sabo, Tibor and Trifunović, Srećko R. and Szecsenyi, KM",
year = "2006",
abstract = "Triammonium-N-dithiocarboxyiminodiacetate, (NH4)(3)L, a new dithiocarbamato derivative of iminodiacetate, has been synthesized. The coordination properties of the ligand were tested in reactions with copper(II), nickel(II) and palladium(II) salts in acidic solutions. Complexes with a general formula M(H2L)(2) were obtained, with the coordination taking place through the sulfur atoms of the dithiocarbamate moiety. The new compounds were characterized by elemental analysis, UV/VIS and IR spectroscopy, thermal analysis and magnetic measurements. In addition, the ligand was characterized by H-1- and C-13-NMR spectroscopy and molar conductivity measurements. The copper(II) complex is paramagnetic, while the nickel(II) and palladium(II) compounds are diamagnetic. The thermal decomposition of all compounds is continuous and the thermal stability of the complexes is higher than that of the ligand, as expected.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Synthesis and physico-chemical characterization of new dithiocarabamato ligand and its complexes with copper(II), nickel(II) and palladium(II)",
volume = "83",
number = "3",
pages = "687-691",
doi = "10.1007/s10973-005-6938-7"
}

Leka, Z., Leovac, V. M., Lukic, S., Sabo, T., Trifunović, S. R.,& Szecsenyi, K.. (2006). Synthesis and physico-chemical characterization of new dithiocarabamato ligand and its complexes with copper(II), nickel(II) and palladium(II). in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 83(3), 687-691.
https://doi.org/10.1007/s10973-005-6938-7

Leka Z, Leovac VM, Lukic S, Sabo T, Trifunović SR, Szecsenyi K. Synthesis and physico-chemical characterization of new dithiocarabamato ligand and its complexes with copper(II), nickel(II) and palladium(II). in Journal of Thermal Analysis and Calorimetry. 2006;83(3):687-691.
doi:10.1007/s10973-005-6938-7 .

Leka, ZB, Leovac, Vukadin M., Lukic, S, Sabo, Tibor, Trifunović, Srećko R., Szecsenyi, KM, "Synthesis and physico-chemical characterization of new dithiocarabamato ligand and its complexes with copper(II), nickel(II) and palladium(II)" in Journal of Thermal Analysis and Calorimetry, 83, no. 3 (2006):687-691,
https://doi.org/10.1007/s10973-005-6938-7 . .

TY  - JOUR
AU  - Leka, Z
AU  - Grujic, SA
AU  - Tešić, Živoslav Lj.
AU  - Lukic, S
AU  - Skuban, S
AU  - Trifunović, Srećko R.
PY  - 2004
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/570
AB  - Complexes of zinc(lI), cadmium(II). platinum(lI) and palladium(II) with a new poly-dentate dithiocarbamate ligand, 3-dithiocarboxy-3-aza-5-aminopentanoate (daap(-)), of the type M(daap)(2).nH(2)O (M = Zn(II), Cd(II), n = 2, or M = Pt(II) Pd(II) n = 0). have been prepared and characterized by elemental analysis. IR and UV/VIS spectroscopy, as well as magnetic measurements. The spectra of the complexes suggest a bidentate coordination of the daap- ligand to the metal ions via the sulfur atoms of the deprotonated dithiocarbamato group. The fact that under the same experimental conditions its S-methyl ester does not form complexes could be taken as proof of the suggested coordination mode.
AB  - Reakcijom između cink(II), kadmijum(II), platina(II) i paladijum(II)-soli i kalijum- 3-ditiokarboksi-3-aza-5-aminopentanoata dobijeni su dogovarajući kompleksi tipa M(daap)2.nH2O. Izolovani kompleksi su okarakterisani elementarnom analizom, IR i UV/VIS spektroskopijom kao i merenjem magnetnih susceptibiliteta. Spektri kompleksa sugerišu bidentatnu koordinaciju daap liganda sa navedenim metalnim jonima preko atoma sumpora deprotonovane ditiokarbamato grupe. Kao dokaz navedenog načina koordinacije može poslužiti činjenica da pri istim eksperimentalnim uslovima S-metil estar liganda ne daje komplekse.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-aminopentanoate
T1  - Sinteza i karakterizacija kompleksa cink(II), kadmijum(II), platina(II),i paladijum(II) sa kalijum-3-ditiokarboksi-3-aza-5-aminopentanoatom
VL  - 69
IS  - 2
SP  - 137
EP  - 143
DO  - 10.2298/JSC0402137L
ER  - 

@article{
author = "Leka, Z and Grujic, SA and Tešić, Živoslav Lj. and Lukic, S and Skuban, S and Trifunović, Srećko R.",
year = "2004",
abstract = "Complexes of zinc(lI), cadmium(II). platinum(lI) and palladium(II) with a new poly-dentate dithiocarbamate ligand, 3-dithiocarboxy-3-aza-5-aminopentanoate (daap(-)), of the type M(daap)(2).nH(2)O (M = Zn(II), Cd(II), n = 2, or M = Pt(II) Pd(II) n = 0). have been prepared and characterized by elemental analysis. IR and UV/VIS spectroscopy, as well as magnetic measurements. The spectra of the complexes suggest a bidentate coordination of the daap- ligand to the metal ions via the sulfur atoms of the deprotonated dithiocarbamato group. The fact that under the same experimental conditions its S-methyl ester does not form complexes could be taken as proof of the suggested coordination mode., Reakcijom između cink(II), kadmijum(II), platina(II) i paladijum(II)-soli i kalijum- 3-ditiokarboksi-3-aza-5-aminopentanoata dobijeni su dogovarajući kompleksi tipa M(daap)2.nH2O. Izolovani kompleksi su okarakterisani elementarnom analizom, IR i UV/VIS spektroskopijom kao i merenjem magnetnih susceptibiliteta. Spektri kompleksa sugerišu bidentatnu koordinaciju daap liganda sa navedenim metalnim jonima preko atoma sumpora deprotonovane ditiokarbamato grupe. Kao dokaz navedenog načina koordinacije može poslužiti činjenica da pri istim eksperimentalnim uslovima S-metil estar liganda ne daje komplekse.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-aminopentanoate, Sinteza i karakterizacija kompleksa cink(II), kadmijum(II), platina(II),i paladijum(II) sa kalijum-3-ditiokarboksi-3-aza-5-aminopentanoatom",
volume = "69",
number = "2",
pages = "137-143",
doi = "10.2298/JSC0402137L"
}

Leka, Z., Grujic, S., Tešić, Ž. Lj., Lukic, S., Skuban, S.,& Trifunović, S. R.. (2004). The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-aminopentanoate. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 69(2), 137-143.
https://doi.org/10.2298/JSC0402137L

Leka Z, Grujic S, Tešić ŽL, Lukic S, Skuban S, Trifunović SR. The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-aminopentanoate. in Journal of the Serbian Chemical Society. 2004;69(2):137-143.
doi:10.2298/JSC0402137L .

Leka, Z, Grujic, SA, Tešić, Živoslav Lj., Lukic, S, Skuban, S, Trifunović, Srećko R., "The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-aminopentanoate" in Journal of the Serbian Chemical Society, 69, no. 2 (2004):137-143,
https://doi.org/10.2298/JSC0402137L . .