Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II)
Abstract
The title compound, [Ni(C20H17N3OP)(N-3)], is the first complex with a semicarbazide-based ligand having a P atom as one of the donors. The influence of the P atom on the deformation of the coordination geometry of the Ni-II ion is evident but less expressed than in the cases of complexes with analogous seleno-and thiosemicarbazide ligands. The torsion angles involving the two bonds formed by the P atom within the six-membered chelate ring have the largest values [C-P-Ni-N = 24.3 (2)degrees and C-C-P-Ni = -24.2 (4)degrees], suggesting that the P atom considerably influences the conformation of the ring. Two types of N-H center dot center dot center dot N hydrogen bond connect the complex units into chains.
Source:
Acta Crystallographica. Section C: Crystal Structure Communications, 2009, 65Publisher:
- Wiley-Blackwell, Malden
Funding / projects:
- Sinteze, fizičke, strukturne i biološke karakteristike novih kompleksnih jedenjenja (RS-MESTD-MPN2006-2010-142028)
DOI: 10.1107/S0108270109021970
ISSN: 0108-2701
PubMed: 19578259
WoS: 000268436500012
Scopus: 2-s2.0-67651165477
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Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Novaković, Sladjana B. AU - Bogdanović, Goran A. AU - Brčeski, Ilija AU - Leovac, Vukadin M. PY - 2009 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1000 AB - The title compound, [Ni(C20H17N3OP)(N-3)], is the first complex with a semicarbazide-based ligand having a P atom as one of the donors. The influence of the P atom on the deformation of the coordination geometry of the Ni-II ion is evident but less expressed than in the cases of complexes with analogous seleno-and thiosemicarbazide ligands. The torsion angles involving the two bonds formed by the P atom within the six-membered chelate ring have the largest values [C-P-Ni-N = 24.3 (2)degrees and C-C-P-Ni = -24.2 (4)degrees], suggesting that the P atom considerably influences the conformation of the ring. Two types of N-H center dot center dot center dot N hydrogen bond connect the complex units into chains. PB - Wiley-Blackwell, Malden T2 - Acta Crystallographica. Section C: Crystal Structure Communications T1 - Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II) VL - 65 DO - 10.1107/S0108270109021970 ER -
@article{ author = "Novaković, Sladjana B. and Bogdanović, Goran A. and Brčeski, Ilija and Leovac, Vukadin M.", year = "2009", abstract = "The title compound, [Ni(C20H17N3OP)(N-3)], is the first complex with a semicarbazide-based ligand having a P atom as one of the donors. The influence of the P atom on the deformation of the coordination geometry of the Ni-II ion is evident but less expressed than in the cases of complexes with analogous seleno-and thiosemicarbazide ligands. The torsion angles involving the two bonds formed by the P atom within the six-membered chelate ring have the largest values [C-P-Ni-N = 24.3 (2)degrees and C-C-P-Ni = -24.2 (4)degrees], suggesting that the P atom considerably influences the conformation of the ring. Two types of N-H center dot center dot center dot N hydrogen bond connect the complex units into chains.", publisher = "Wiley-Blackwell, Malden", journal = "Acta Crystallographica. Section C: Crystal Structure Communications", title = "Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II)", volume = "65", doi = "10.1107/S0108270109021970" }
Novaković, S. B., Bogdanović, G. A., Brčeski, I.,& Leovac, V. M.. (2009). Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II). in Acta Crystallographica. Section C: Crystal Structure Communications Wiley-Blackwell, Malden., 65. https://doi.org/10.1107/S0108270109021970
Novaković SB, Bogdanović GA, Brčeski I, Leovac VM. Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II). in Acta Crystallographica. Section C: Crystal Structure Communications. 2009;65. doi:10.1107/S0108270109021970 .
Novaković, Sladjana B., Bogdanović, Goran A., Brčeski, Ilija, Leovac, Vukadin M., "Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II)" in Acta Crystallographica. Section C: Crystal Structure Communications, 65 (2009), https://doi.org/10.1107/S0108270109021970 . .