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dc.creatorRatkovic, Zoran
dc.creatorNovaković, Slađana B.
dc.creatorBogdanović, Goran A.
dc.creatorŠegan, Dejan M.
dc.creatorVukicevic, Rastko D.
dc.date.accessioned2018-11-22T00:16:42Z
dc.date.available2018-11-22T00:16:42Z
dc.date.issued2010
dc.identifier.issn0277-5387
dc.identifier.urihttp://cherry.chem.bg.ac.rs/handle/123456789/1098
dc.description.abstractThe one-pot synthesis of seven new (2-alkylthiobenzoyl)ferrocenes has been achieved by Friedel-Crafts acylation of ferrocene with acid chlorides generated in situ from the corresponding carboxylic acids and phosphorous trichloride. The obtained compounds were characterized by spectroscopic data (UV, IR, (1)H and (13)C NMR), whereas their electrochemical properties have been investigated by cyclic voltammetry. The single-crystal X-ray structure determinations for three of them are also reported. Each of the three derivatives exhibits the intramolecular C-H center dot center dot center dot O interaction which involves the donor from the cyclopentadienyl (Cp) ring and the carbonyl oxygen as acceptor. This interaction favors the coplanar arrangement of the two moieties. The angles between the vectors coinciding the C-O bonds and the corresponding Cp planes are all below 6.4 degrees. Conventional hydrogen bonds do not exist in any of the three crystal structures but some weak intermolecular interactions of the C-H center dot center dot center dot, C-H center dot center dot center dot S and C-H center dot center dot center dot pi types have been found and analyzed in detail. Different geometrical parameters for these crystal structures as well as for 22 similar ones extracted from Cambridge Structural Database (CSD) have been compared and analyzed. (C) 2010 Elsevier Ltd. All rights reserved.en
dc.publisherPergamon-Elsevier Science Ltd, Oxford
dc.relationinfo:eu-repo/grantAgreement/MESTD/MPN2006-2010/142042/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/MPN2006-2010/142010/RS//
dc.rightsrestrictedAccess
dc.sourcePolyhedron
dc.subjectFerroceneen
dc.subject2-Alkylthiobenzoic acidsen
dc.subject(2-Alkylthiobenzoyl)ferrocenesen
dc.subjectCyclic voltammetryen
dc.subjectCrystal structureen
dc.subjectC-H center dot center dot center dot pi interactionsen
dc.titleSynthesis, spectral characterization and electrochemical properties of (2-alkylthiobenzoyl)ferrocenes. Crystal structures of 2-methylthio, 2-ethylthio and 2-isopropylthio derivativesen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractШеган, Дејан; Вукицевиц, Растко Д.; Богдановиц, Горан A.; Ратковиц, Зоран; Новаковиц, Сладана Б.;
dc.citation.volume29
dc.citation.issue11
dc.citation.spage2311
dc.citation.epage2317
dc.identifier.wos000280634300011
dc.identifier.doi10.1016/j.poly.2010.04.034
dc.citation.other29(11): 2311-2317
dc.citation.rankM22
dc.type.versionpublishedVersionen
dc.identifier.scopus2-s2.0-77954621246
dc.identifier.rcubKon_2098


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