Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups
Само за регистроване кориснике
2012
Аутори
Filipović, Nenad R.Todorović, Tamara
Radanović, Dušanka D.
Divjaković, Vladimir
Marković, Rade
Pajic, Ivana
Anđelković, Katarina K.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Two novel cadmium(II) complexes with condensation derivatives of 2-acetylpyridine or 2,6-diacetylpyridine with ethyl hydrazinoacetate hydrochloride were synthesized. X-ray crystal structures of the complexes revealed a bidentate coordination of the 2-acetylpyridine derivative, while the symmetric 2,6-diacetylpyridine derivative was coordinated tridentately. It was found that the oxygen atoms were not coordinated to the cadmium ions, despite the fact that they are the position to form six membered chelate rings. NMR spectroscopy investigations showed that the coordination properties of the ligands do not change in solution. Both complexes possess cytotoxic potential, as determined by the toxicity test to Artemia (C) 2011 Published by Elsevier Ltd.
Кључне речи:
Cd(II) complexes / N-Heteroaromatic hydrazones / X-ray analysis / NMR spectroscopy / Biological activityИзвор:
Polyhedron, 2012, 31, 1, 19-28Издавач:
- Pergamon-Elsevier Science Ltd, Oxford
Финансирање / пројекти:
- Интеракције природних производа, њихових деривата и комплексних једињења са протеинима и нуклеинским киселинама (RS-MESTD-Basic Research (BR or ON)-172055)
DOI: 10.1016/j.poly.2011.07.023
ISSN: 0277-5387
WoS: 000300642900003
Scopus: 2-s2.0-84155163213
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Filipović, Nenad R. AU - Todorović, Tamara AU - Radanović, Dušanka D. AU - Divjaković, Vladimir AU - Marković, Rade AU - Pajic, Ivana AU - Anđelković, Katarina K. PY - 2012 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1255 AB - Two novel cadmium(II) complexes with condensation derivatives of 2-acetylpyridine or 2,6-diacetylpyridine with ethyl hydrazinoacetate hydrochloride were synthesized. X-ray crystal structures of the complexes revealed a bidentate coordination of the 2-acetylpyridine derivative, while the symmetric 2,6-diacetylpyridine derivative was coordinated tridentately. It was found that the oxygen atoms were not coordinated to the cadmium ions, despite the fact that they are the position to form six membered chelate rings. NMR spectroscopy investigations showed that the coordination properties of the ligands do not change in solution. Both complexes possess cytotoxic potential, as determined by the toxicity test to Artemia (C) 2011 Published by Elsevier Ltd. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Polyhedron T1 - Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups VL - 31 IS - 1 SP - 19 EP - 28 DO - 10.1016/j.poly.2011.07.023 ER -
@article{ author = "Filipović, Nenad R. and Todorović, Tamara and Radanović, Dušanka D. and Divjaković, Vladimir and Marković, Rade and Pajic, Ivana and Anđelković, Katarina K.", year = "2012", abstract = "Two novel cadmium(II) complexes with condensation derivatives of 2-acetylpyridine or 2,6-diacetylpyridine with ethyl hydrazinoacetate hydrochloride were synthesized. X-ray crystal structures of the complexes revealed a bidentate coordination of the 2-acetylpyridine derivative, while the symmetric 2,6-diacetylpyridine derivative was coordinated tridentately. It was found that the oxygen atoms were not coordinated to the cadmium ions, despite the fact that they are the position to form six membered chelate rings. NMR spectroscopy investigations showed that the coordination properties of the ligands do not change in solution. Both complexes possess cytotoxic potential, as determined by the toxicity test to Artemia (C) 2011 Published by Elsevier Ltd.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Polyhedron", title = "Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups", volume = "31", number = "1", pages = "19-28", doi = "10.1016/j.poly.2011.07.023" }
Filipović, N. R., Todorović, T., Radanović, D. D., Divjaković, V., Marković, R., Pajic, I.,& Anđelković, K. K.. (2012). Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups. in Polyhedron Pergamon-Elsevier Science Ltd, Oxford., 31(1), 19-28. https://doi.org/10.1016/j.poly.2011.07.023
Filipović NR, Todorović T, Radanović DD, Divjaković V, Marković R, Pajic I, Anđelković KK. Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups. in Polyhedron. 2012;31(1):19-28. doi:10.1016/j.poly.2011.07.023 .
Filipović, Nenad R., Todorović, Tamara, Radanović, Dušanka D., Divjaković, Vladimir, Marković, Rade, Pajic, Ivana, Anđelković, Katarina K., "Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups" in Polyhedron, 31, no. 1 (2012):19-28, https://doi.org/10.1016/j.poly.2011.07.023 . .