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dc.creatorSpasojevic, Ivan
dc.creatorPristov, Jelena Bogdanovic
dc.creatorVujisić, Ljubodrag V.
dc.creatorSpasic, Mihajlo
dc.date.accessioned2018-11-22T00:21:17Z
dc.date.available2018-11-22T00:21:17Z
dc.date.issued2012
dc.identifier.issn0939-4451
dc.identifier.urihttp://cherry.chem.bg.ac.rs/handle/123456789/1297
dc.description.abstractThe mechanisms of reaction of methionine with hydroxyl radical are not fully understood. Here, we unequivocally show using electron paramagnetic resonance spin-trapping spectroscopy and GC-FID and GC-MS, the presence of specific carbon-, nitrogen- and sulfur-centered radicals as intermediates of this reaction, as well as the liberation of methanethiol as a gaseous end product. Taking into account the many roles that methionine has in eco- and biosystems, our results may elucidate redox chemistry of this amino acid and processes that methionine is involved in.en
dc.publisherSpringer Wien, Wien
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/173014/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/173017/RS//
dc.rightsrestrictedAccess
dc.sourceAmino Acids
dc.subjectMethionineen
dc.subjectHydroxyl radicalen
dc.subjectEPRen
dc.subjectGCen
dc.subjectFree radicalen
dc.subjectMethanethiolen
dc.titleThe reaction of methionine with hydroxyl radical: reactive intermediates and methanethiol productionen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractПристов, Јелена Богдановиц; Спасиц, Михајло; Вујисић, Љубодраг; Спасојевиц, Иван;
dc.citation.volume42
dc.citation.issue6
dc.citation.spage2439
dc.citation.epage2445
dc.identifier.wos000304150300042
dc.identifier.doi10.1007/s00726-011-1049-1
dc.citation.other42(6): 2439-2445
dc.citation.rankM21
dc.identifier.pmid21830117
dc.type.versionpublishedVersionen
dc.identifier.scopus2-s2.0-84862754980
dc.identifier.rcubKon_2320


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