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The reaction of methionine with hydroxyl radical: reactive intermediates and methanethiol production
dc.creator | Spasojević, Ivan | |
dc.creator | Pristov-Bogdanović, Jelena | |
dc.creator | Vujisić, Ljubodrag V. | |
dc.creator | Spasić, Mihajlo B. | |
dc.date.accessioned | 2018-11-22T00:21:17Z | |
dc.date.available | 2018-11-22T00:21:17Z | |
dc.date.issued | 2012 | |
dc.identifier.issn | 0939-4451 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/1297 | |
dc.description.abstract | The mechanisms of reaction of methionine with hydroxyl radical are not fully understood. Here, we unequivocally show using electron paramagnetic resonance spin-trapping spectroscopy and GC-FID and GC-MS, the presence of specific carbon-, nitrogen- and sulfur-centered radicals as intermediates of this reaction, as well as the liberation of methanethiol as a gaseous end product. Taking into account the many roles that methionine has in eco- and biosystems, our results may elucidate redox chemistry of this amino acid and processes that methionine is involved in. | en |
dc.publisher | Springer Wien, Wien | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/173014/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/173017/RS// | |
dc.rights | restrictedAccess | |
dc.source | Amino Acids | |
dc.subject | Methionine | en |
dc.subject | Hydroxyl radical | en |
dc.subject | EPR | en |
dc.subject | GC | en |
dc.subject | Free radical | en |
dc.subject | Methanethiol | en |
dc.title | The reaction of methionine with hydroxyl radical: reactive intermediates and methanethiol production | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Пристов, Јелена Богдановиц; Спасиц, Михајло; Вујисић, Љубодраг; Спасојевиц, Иван; | |
dc.citation.volume | 42 | |
dc.citation.issue | 6 | |
dc.citation.spage | 2439 | |
dc.citation.epage | 2445 | |
dc.identifier.wos | 000304150300042 | |
dc.identifier.doi | 10.1007/s00726-011-1049-1 | |
dc.citation.other | 42(6): 2439-2445 | |
dc.citation.rank | M21 | |
dc.identifier.pmid | 21830117 | |
dc.type.version | publishedVersion | en |
dc.identifier.scopus | 2-s2.0-84862754980 |