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dc.creatorChen, Shigui
dc.creatorRuan, Yian
dc.creatorBrown, Jason D.
dc.creatorGallucci, Judith
dc.creatorMaslak, Veselin
dc.creatorHadad, Christopher M.
dc.creatorBađić, Jovica D.
dc.date.accessioned2018-11-22T00:24:23Z
dc.date.available2018-11-22T00:24:23Z
dc.date.issued2013
dc.identifier.issn0002-7863
dc.identifier.urihttp://cherry.chem.bg.ac.rs/handle/123456789/1427
dc.description.abstractWe designed basket 1 to comprise a C-3-symmetric hydrophobic cage (477 angstrom(3)) at its southern edge and three polar ammonium caps at the northern edge. This amphiphilic molecule was observed to assemble into large unilamellar vesicles (350 nm, TEM) in water and thereby entrap dimethyl phenylphosphonate (184 angstrom(3)) in its cavity (K-app = (1.97 +/- 0.02) X 10(3) M-1). The entrapment of the organophosphonate, akin to soman in size (186 angstrom(3)), triggers the transformation of the vesicular material into nanoparticles (100 nm,of type 1 in their bilayer membrane, are unique assemblies and important for obtaining novel sensing devices.en
dc.publisherAmer Chemical Soc, Washington
dc.relationDepartment of Defense, Defense Threat Reduction Agency [HDTRA1-11-1-0042]
dc.rightsrestrictedAccess
dc.sourceJournal of the American Chemical Society
dc.titleAssembly of Amphiphilic Baskets into Stimuli-Responsive Vesicles. Developing a Strategy for the Detection of Organophosphorus Chemical Nerve Agentsen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractГаллуцци, Јудитх; Броwн, Јасон Д.; Хадад, Цхристопхер М.; Цхен, Схигуи; Руан, Yиан; Маслак, Веселин; Бадјиц, Јовица Д.;
dc.citation.volume135
dc.citation.issue40
dc.citation.spage14964
dc.citation.epage14967
dc.identifier.wos000326356400018
dc.identifier.doi10.1021/ja408585j
dc.citation.other135(40): 14964-14967
dc.citation.rankaM21
dc.identifier.pmid24063351
dc.description.otherSupplementary material: [http://cherry.chem.bg.ac.rs/handle/123456789/3469]
dc.type.versionpublishedVersionen
dc.identifier.scopus2-s2.0-84885577274
dc.identifier.rcubKon_2547


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