Analysis of the structures of the Cu(I) and Cu(II) complexes with 3-acetylpyridine and thiocyanate
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2014
Authors
Čobeljić, BožidarPevec, Andrej
Turel, Iztok
Spasojević, Vojislav
Milčić, Miloš K.
Mitić, Dragana
Sladić, Dušan
Anđelković, Katarina K.
Article (Published version)
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Show full item recordAbstract
3-Acetylpyridine thiosemicarbazone hydrochloride was synthesized and structurally characterized. Complexes of Cu(II) with this ligand could not be obtained by direct synthesis. By synthesis in situ mixing Cu(BF4)(2)center dot 6H(2)O, 3-acetylpyridine (3-Acpy) and semicarbazide, a Cu(I) polymer, {[Cu(SCN)(3-Acpy)(2)]}(n) was obtained and structurally characterized. Reaction of Cu(BF4)(2)center dot 6H(2)O, 3-acetylpyridine and ammonium thiocyanate afforded a dinuclear Cu(II) complex with two thiocyanate ions in bridges, which was structurally characterized. Magnetic measurements were performed for the dinuclear complex. OFT calculations provided explanation for inability to obtain a mononuclear complex. (C) 2013 Elsevier Ltd. All rights reserved.
Keywords:
Cu(I) and Cu(II) complexes / 3-Acetylpyridine / Thiocyanate / DFT calculations / Magnetic propertiesSource:
Polyhedron, 2014, 69, 77-83Publisher:
- Pergamon-Elsevier Science Ltd, Oxford
Funding / projects:
- Interactions of natural products, their derivatives and coordination compounds with proteins and nucleic acids (RS-MESTD-Basic Research (BR or ON)-172055)
- Slovenian Research Agency (ARRS) [P-0175]
Note:
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3671
DOI: 10.1016/j.poly.2013.11.027
ISSN: 0277-5387
WoS: 000331502500011
Scopus: 2-s2.0-84890443353
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Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Čobeljić, Božidar AU - Pevec, Andrej AU - Turel, Iztok AU - Spasojević, Vojislav AU - Milčić, Miloš K. AU - Mitić, Dragana AU - Sladić, Dušan AU - Anđelković, Katarina K. PY - 2014 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1506 AB - 3-Acetylpyridine thiosemicarbazone hydrochloride was synthesized and structurally characterized. Complexes of Cu(II) with this ligand could not be obtained by direct synthesis. By synthesis in situ mixing Cu(BF4)(2)center dot 6H(2)O, 3-acetylpyridine (3-Acpy) and semicarbazide, a Cu(I) polymer, {[Cu(SCN)(3-Acpy)(2)]}(n) was obtained and structurally characterized. Reaction of Cu(BF4)(2)center dot 6H(2)O, 3-acetylpyridine and ammonium thiocyanate afforded a dinuclear Cu(II) complex with two thiocyanate ions in bridges, which was structurally characterized. Magnetic measurements were performed for the dinuclear complex. OFT calculations provided explanation for inability to obtain a mononuclear complex. (C) 2013 Elsevier Ltd. All rights reserved. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Polyhedron T1 - Analysis of the structures of the Cu(I) and Cu(II) complexes with 3-acetylpyridine and thiocyanate VL - 69 SP - 77 EP - 83 DO - 10.1016/j.poly.2013.11.027 ER -
@article{ author = "Čobeljić, Božidar and Pevec, Andrej and Turel, Iztok and Spasojević, Vojislav and Milčić, Miloš K. and Mitić, Dragana and Sladić, Dušan and Anđelković, Katarina K.", year = "2014", abstract = "3-Acetylpyridine thiosemicarbazone hydrochloride was synthesized and structurally characterized. Complexes of Cu(II) with this ligand could not be obtained by direct synthesis. By synthesis in situ mixing Cu(BF4)(2)center dot 6H(2)O, 3-acetylpyridine (3-Acpy) and semicarbazide, a Cu(I) polymer, {[Cu(SCN)(3-Acpy)(2)]}(n) was obtained and structurally characterized. Reaction of Cu(BF4)(2)center dot 6H(2)O, 3-acetylpyridine and ammonium thiocyanate afforded a dinuclear Cu(II) complex with two thiocyanate ions in bridges, which was structurally characterized. Magnetic measurements were performed for the dinuclear complex. OFT calculations provided explanation for inability to obtain a mononuclear complex. (C) 2013 Elsevier Ltd. All rights reserved.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Polyhedron", title = "Analysis of the structures of the Cu(I) and Cu(II) complexes with 3-acetylpyridine and thiocyanate", volume = "69", pages = "77-83", doi = "10.1016/j.poly.2013.11.027" }
Čobeljić, B., Pevec, A., Turel, I., Spasojević, V., Milčić, M. K., Mitić, D., Sladić, D.,& Anđelković, K. K.. (2014). Analysis of the structures of the Cu(I) and Cu(II) complexes with 3-acetylpyridine and thiocyanate. in Polyhedron Pergamon-Elsevier Science Ltd, Oxford., 69, 77-83. https://doi.org/10.1016/j.poly.2013.11.027
Čobeljić B, Pevec A, Turel I, Spasojević V, Milčić MK, Mitić D, Sladić D, Anđelković KK. Analysis of the structures of the Cu(I) and Cu(II) complexes with 3-acetylpyridine and thiocyanate. in Polyhedron. 2014;69:77-83. doi:10.1016/j.poly.2013.11.027 .
Čobeljić, Božidar, Pevec, Andrej, Turel, Iztok, Spasojević, Vojislav, Milčić, Miloš K., Mitić, Dragana, Sladić, Dušan, Anđelković, Katarina K., "Analysis of the structures of the Cu(I) and Cu(II) complexes with 3-acetylpyridine and thiocyanate" in Polyhedron, 69 (2014):77-83, https://doi.org/10.1016/j.poly.2013.11.027 . .