Effects of Eu3+ Concentration on Structural, Optical and Vibrational Properties of Multifunctional Ce1-X,EuXO2-delta Nanoparticles Synthesized by Thermolysis of 2,4-Pentanedione Complexes
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Аутори
Kremenović, AleksandarBozanic, D. K.
Welsch, A. -M.
Jancar, B.
Nikolić, Aleksandar S.
Bošković, Marko
Colomban, Ph.
Fabian, Martin
Antić, Bratislav
Чланак у часопису (Објављена верзија)
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Приказ свих података о документуАпстракт
The 5-10 nnn Ce1-XEuXO2-delta (0 lt = x lt = 0.30) nanoparticles with fluorite structure were synthesized by thermal decomposition of Eu- and Ce-2,4-pentanedione complexes mixtures. X-ray line broadening analysis of mixed samples Ce1-XEuXO2-delta (0.05 lt = x lt = 0.30) showed that the crystallite size was lower and root mean square strain higher than in pure ceria. However, within mixed samples Ce1-XEuXO2-delta (0.05 lt = x lt = 0.30) crystallite size and root mean square strain were independent of Eu3+ concentration. Raman spectroscopy results indicated that europium ions yield disorder by breaking the phonon propagation and therefore making the non-centre Brillouin zone modes Raman active. The absorption bands in the spectra of mixed oxides were blue-shifted in comparison to pure CeO2-delta nanopowder. The samples show red emission typical for Eu ions. The biggest photoluminescent intensity was observed for the highest Eu3+ concentration (x = 0.30) and further enhanced with th...e increase in crystallinity.
Кључне речи:
Ceria / Nanoparticles / Synthesis / Spectroscopy / StructureИзвор:
Journal of Nanoscience and Nanotechnology, 2012, 12, 12, 8893-8899Издавач:
- Amer Scientific Publishers, Valencia
Финансирање / пројекти:
- Магнетни и радионуклидима обележени наноструктурни материјали за примене у медицини (RS-45015)
- Рационални дизајн и синтеза биолошки активних и координационих једињења и функционалних материјала, релевантних у (био)нанотехнологији (RS-172035)
DOI: 10.1166/jnn.2012.6797
ISSN: 1533-4880
PubMed: 23447934
WoS: 000315172400006
Scopus: 2-s2.0-84876275113
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Kremenović, Aleksandar AU - Bozanic, D. K. AU - Welsch, A. -M. AU - Jancar, B. AU - Nikolić, Aleksandar S. AU - Bošković, Marko AU - Colomban, Ph. AU - Fabian, Martin AU - Antić, Bratislav PY - 2012 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1603 AB - The 5-10 nnn Ce1-XEuXO2-delta (0 lt = x lt = 0.30) nanoparticles with fluorite structure were synthesized by thermal decomposition of Eu- and Ce-2,4-pentanedione complexes mixtures. X-ray line broadening analysis of mixed samples Ce1-XEuXO2-delta (0.05 lt = x lt = 0.30) showed that the crystallite size was lower and root mean square strain higher than in pure ceria. However, within mixed samples Ce1-XEuXO2-delta (0.05 lt = x lt = 0.30) crystallite size and root mean square strain were independent of Eu3+ concentration. Raman spectroscopy results indicated that europium ions yield disorder by breaking the phonon propagation and therefore making the non-centre Brillouin zone modes Raman active. The absorption bands in the spectra of mixed oxides were blue-shifted in comparison to pure CeO2-delta nanopowder. The samples show red emission typical for Eu ions. The biggest photoluminescent intensity was observed for the highest Eu3+ concentration (x = 0.30) and further enhanced with the increase in crystallinity. PB - Amer Scientific Publishers, Valencia T2 - Journal of Nanoscience and Nanotechnology T1 - Effects of Eu3+ Concentration on Structural, Optical and Vibrational Properties of Multifunctional Ce1-X,EuXO2-delta Nanoparticles Synthesized by Thermolysis of 2,4-Pentanedione Complexes VL - 12 IS - 12 SP - 8893 EP - 8899 DO - 10.1166/jnn.2012.6797 ER -
@article{ author = "Kremenović, Aleksandar and Bozanic, D. K. and Welsch, A. -M. and Jancar, B. and Nikolić, Aleksandar S. and Bošković, Marko and Colomban, Ph. and Fabian, Martin and Antić, Bratislav", year = "2012", abstract = "The 5-10 nnn Ce1-XEuXO2-delta (0 lt = x lt = 0.30) nanoparticles with fluorite structure were synthesized by thermal decomposition of Eu- and Ce-2,4-pentanedione complexes mixtures. X-ray line broadening analysis of mixed samples Ce1-XEuXO2-delta (0.05 lt = x lt = 0.30) showed that the crystallite size was lower and root mean square strain higher than in pure ceria. However, within mixed samples Ce1-XEuXO2-delta (0.05 lt = x lt = 0.30) crystallite size and root mean square strain were independent of Eu3+ concentration. Raman spectroscopy results indicated that europium ions yield disorder by breaking the phonon propagation and therefore making the non-centre Brillouin zone modes Raman active. The absorption bands in the spectra of mixed oxides were blue-shifted in comparison to pure CeO2-delta nanopowder. The samples show red emission typical for Eu ions. The biggest photoluminescent intensity was observed for the highest Eu3+ concentration (x = 0.30) and further enhanced with the increase in crystallinity.", publisher = "Amer Scientific Publishers, Valencia", journal = "Journal of Nanoscience and Nanotechnology", title = "Effects of Eu3+ Concentration on Structural, Optical and Vibrational Properties of Multifunctional Ce1-X,EuXO2-delta Nanoparticles Synthesized by Thermolysis of 2,4-Pentanedione Complexes", volume = "12", number = "12", pages = "8893-8899", doi = "10.1166/jnn.2012.6797" }
Kremenović, A., Bozanic, D. K., Welsch, A. -M., Jancar, B., Nikolić, A. S., Bošković, M., Colomban, Ph., Fabian, M.,& Antić, B.. (2012). Effects of Eu3+ Concentration on Structural, Optical and Vibrational Properties of Multifunctional Ce1-X,EuXO2-delta Nanoparticles Synthesized by Thermolysis of 2,4-Pentanedione Complexes. in Journal of Nanoscience and Nanotechnology Amer Scientific Publishers, Valencia., 12(12), 8893-8899. https://doi.org/10.1166/jnn.2012.6797
Kremenović A, Bozanic DK, Welsch A-, Jancar B, Nikolić AS, Bošković M, Colomban P, Fabian M, Antić B. Effects of Eu3+ Concentration on Structural, Optical and Vibrational Properties of Multifunctional Ce1-X,EuXO2-delta Nanoparticles Synthesized by Thermolysis of 2,4-Pentanedione Complexes. in Journal of Nanoscience and Nanotechnology. 2012;12(12):8893-8899. doi:10.1166/jnn.2012.6797 .
Kremenović, Aleksandar, Bozanic, D. K., Welsch, A. -M., Jancar, B., Nikolić, Aleksandar S., Bošković, Marko, Colomban, Ph., Fabian, Martin, Antić, Bratislav, "Effects of Eu3+ Concentration on Structural, Optical and Vibrational Properties of Multifunctional Ce1-X,EuXO2-delta Nanoparticles Synthesized by Thermolysis of 2,4-Pentanedione Complexes" in Journal of Nanoscience and Nanotechnology, 12, no. 12 (2012):8893-8899, https://doi.org/10.1166/jnn.2012.6797 . .