Organic Geochemical Study of the Lower Miocene Kremna Basin, Serbia
Нема приказа
Аутори
Perunović, TamaraStojanović, Ksenija A.
Simić, Vladimir
Kašanin-Grubin, Milica
Šajnović, Aleksandra
Eric, Vladisav
Schwarzbauer, Jan
Vasić, Nebojša
Jovančićević, Branimir
Brčeski, Ilija
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The Kremna Basin is located in south west Serbia, in the Zlatibor area, which is part of the Internal Dinarides. This basin is note worthy because of the type of bedrock drainage, which it represents. It was formed on ultrabasic rocks and volcanic materials that influenced the occurrence of organic matter (OM) in the basin fill. The objective of the study was to determine the organic geochemical characteristics of sediments from the central part of the Kremna Basin. The sediments studied belong to an intrabasinal facies, in which two sequences were distinguished. The lower sequence occurs at depths of 216-343 m, while the upper sequence is found from 13.5-216 m. At the start of basin development (265-343 m) sedimentation took place in shallow alkaline water, rich in Mg ions. Through time, a slight deepening of the basin occurred. This was followed by chemical deposition of carbonates (216-265 m). The most important change in the sedimentary environment occurred with the formation of se...diments marking the transition between the sequences (at about 200 m). Sediments from the lower sequence are characterized by the dominance of dolomite and magnesite. There are indications of volcanic activity, i.e. tuff layers and the presence of searlesite. The upper sequence is characterized by the prevalence of calcite and dolomite. The amounts of MgO, Na2O and B are higher in the lower sequence, whereas the CaO content is higher in the upper sequence. The sediments contain different amounts of immature OM (late diagenesis). Biomarker analysis shows diverse precursors of the sedimentary OM: methanogenic archaea, photosynthetic green sulfur bacteria (Chlorobiaceae), bacterivorous ciliates, various bacteria, both photosynthetic and non-photosynthetic, the green unicellular microalga, Botryococcus braunii race A (exclusively in the upper sequence) and terrestrial plants. The lower sequence contains lower amount OM, composed primarily of kerogen II/III and III types, indicating a higher contribution of the allochtonous biomass of land plants from the lake catchment, particularly in the lower part. The sediments of the upper sequence are enriched in autochthonous aquatic OM, which comprises mostly kerogen I, I/II and II types. The transition from the lower sequence to the upper one is associated with a decrease in pristane to phytane ratio, gammacerane index and content of C-28 steroids, absence or significantly lower amount of squalane, absence of C-24 and C-25 regular isoprenoids, 8-methyl-2-methyl-2-(4,8,12-trimethyltridecyl) chroman and C-30 hop-17(21)-ene. Pyrolytic experiments showed that the sediments of the upper sequence, rich in aquatic OM, at a catagenetic stage could be a source of liquid hydrocarbons. The values of hopane, sterane and phenanthrene maturation parameters indicate that through pyrolysis at 400 degrees C the samples investigated reached a value of vitrinite reflectance equivalent of approximately 0.70%. It was estimated that the sediments should be found at depths of 2300-2900 m in order to become active source rocks. The calculated minimum temperature, necessary for catagenetic hydrocarbon generation, is between 103 and 107 degrees C.
Кључне речи:
Kremna Basin / lacustrine sediments / organic matter / mineralogy / biomarkers / pyrolysisИзвор:
Annales Societatis Geologorum Poloniae, 2014, 84, 3, 185-212Издавач:
- Polish Geological Soc, Krakow
Финансирање / пројекти:
- Геохемијска испитивања седиментних стена - фосилна горива и загађивачи животне средине (RS-MESTD-Basic Research (BR or ON)-176006)
- Магматизам и геодинамика Балканског полуострва од мезозоика до данас: значај за образовање металичних и неметаличних рудних лежишта (RS-MESTD-Basic Research (BR or ON)-176016)
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Perunović, Tamara AU - Stojanović, Ksenija A. AU - Simić, Vladimir AU - Kašanin-Grubin, Milica AU - Šajnović, Aleksandra AU - Eric, Vladisav AU - Schwarzbauer, Jan AU - Vasić, Nebojša AU - Jovančićević, Branimir AU - Brčeski, Ilija PY - 2014 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1645 AB - The Kremna Basin is located in south west Serbia, in the Zlatibor area, which is part of the Internal Dinarides. This basin is note worthy because of the type of bedrock drainage, which it represents. It was formed on ultrabasic rocks and volcanic materials that influenced the occurrence of organic matter (OM) in the basin fill. The objective of the study was to determine the organic geochemical characteristics of sediments from the central part of the Kremna Basin. The sediments studied belong to an intrabasinal facies, in which two sequences were distinguished. The lower sequence occurs at depths of 216-343 m, while the upper sequence is found from 13.5-216 m. At the start of basin development (265-343 m) sedimentation took place in shallow alkaline water, rich in Mg ions. Through time, a slight deepening of the basin occurred. This was followed by chemical deposition of carbonates (216-265 m). The most important change in the sedimentary environment occurred with the formation of sediments marking the transition between the sequences (at about 200 m). Sediments from the lower sequence are characterized by the dominance of dolomite and magnesite. There are indications of volcanic activity, i.e. tuff layers and the presence of searlesite. The upper sequence is characterized by the prevalence of calcite and dolomite. The amounts of MgO, Na2O and B are higher in the lower sequence, whereas the CaO content is higher in the upper sequence. The sediments contain different amounts of immature OM (late diagenesis). Biomarker analysis shows diverse precursors of the sedimentary OM: methanogenic archaea, photosynthetic green sulfur bacteria (Chlorobiaceae), bacterivorous ciliates, various bacteria, both photosynthetic and non-photosynthetic, the green unicellular microalga, Botryococcus braunii race A (exclusively in the upper sequence) and terrestrial plants. The lower sequence contains lower amount OM, composed primarily of kerogen II/III and III types, indicating a higher contribution of the allochtonous biomass of land plants from the lake catchment, particularly in the lower part. The sediments of the upper sequence are enriched in autochthonous aquatic OM, which comprises mostly kerogen I, I/II and II types. The transition from the lower sequence to the upper one is associated with a decrease in pristane to phytane ratio, gammacerane index and content of C-28 steroids, absence or significantly lower amount of squalane, absence of C-24 and C-25 regular isoprenoids, 8-methyl-2-methyl-2-(4,8,12-trimethyltridecyl) chroman and C-30 hop-17(21)-ene. Pyrolytic experiments showed that the sediments of the upper sequence, rich in aquatic OM, at a catagenetic stage could be a source of liquid hydrocarbons. The values of hopane, sterane and phenanthrene maturation parameters indicate that through pyrolysis at 400 degrees C the samples investigated reached a value of vitrinite reflectance equivalent of approximately 0.70%. It was estimated that the sediments should be found at depths of 2300-2900 m in order to become active source rocks. The calculated minimum temperature, necessary for catagenetic hydrocarbon generation, is between 103 and 107 degrees C. PB - Polish Geological Soc, Krakow T2 - Annales Societatis Geologorum Poloniae T1 - Organic Geochemical Study of the Lower Miocene Kremna Basin, Serbia VL - 84 IS - 3 SP - 185 EP - 212 UR - https://hdl.handle.net/21.15107/rcub_cherry_1645 ER -
@article{ author = "Perunović, Tamara and Stojanović, Ksenija A. and Simić, Vladimir and Kašanin-Grubin, Milica and Šajnović, Aleksandra and Eric, Vladisav and Schwarzbauer, Jan and Vasić, Nebojša and Jovančićević, Branimir and Brčeski, Ilija", year = "2014", abstract = "The Kremna Basin is located in south west Serbia, in the Zlatibor area, which is part of the Internal Dinarides. This basin is note worthy because of the type of bedrock drainage, which it represents. It was formed on ultrabasic rocks and volcanic materials that influenced the occurrence of organic matter (OM) in the basin fill. The objective of the study was to determine the organic geochemical characteristics of sediments from the central part of the Kremna Basin. The sediments studied belong to an intrabasinal facies, in which two sequences were distinguished. The lower sequence occurs at depths of 216-343 m, while the upper sequence is found from 13.5-216 m. At the start of basin development (265-343 m) sedimentation took place in shallow alkaline water, rich in Mg ions. Through time, a slight deepening of the basin occurred. This was followed by chemical deposition of carbonates (216-265 m). The most important change in the sedimentary environment occurred with the formation of sediments marking the transition between the sequences (at about 200 m). Sediments from the lower sequence are characterized by the dominance of dolomite and magnesite. There are indications of volcanic activity, i.e. tuff layers and the presence of searlesite. The upper sequence is characterized by the prevalence of calcite and dolomite. The amounts of MgO, Na2O and B are higher in the lower sequence, whereas the CaO content is higher in the upper sequence. The sediments contain different amounts of immature OM (late diagenesis). Biomarker analysis shows diverse precursors of the sedimentary OM: methanogenic archaea, photosynthetic green sulfur bacteria (Chlorobiaceae), bacterivorous ciliates, various bacteria, both photosynthetic and non-photosynthetic, the green unicellular microalga, Botryococcus braunii race A (exclusively in the upper sequence) and terrestrial plants. The lower sequence contains lower amount OM, composed primarily of kerogen II/III and III types, indicating a higher contribution of the allochtonous biomass of land plants from the lake catchment, particularly in the lower part. The sediments of the upper sequence are enriched in autochthonous aquatic OM, which comprises mostly kerogen I, I/II and II types. The transition from the lower sequence to the upper one is associated with a decrease in pristane to phytane ratio, gammacerane index and content of C-28 steroids, absence or significantly lower amount of squalane, absence of C-24 and C-25 regular isoprenoids, 8-methyl-2-methyl-2-(4,8,12-trimethyltridecyl) chroman and C-30 hop-17(21)-ene. Pyrolytic experiments showed that the sediments of the upper sequence, rich in aquatic OM, at a catagenetic stage could be a source of liquid hydrocarbons. The values of hopane, sterane and phenanthrene maturation parameters indicate that through pyrolysis at 400 degrees C the samples investigated reached a value of vitrinite reflectance equivalent of approximately 0.70%. It was estimated that the sediments should be found at depths of 2300-2900 m in order to become active source rocks. The calculated minimum temperature, necessary for catagenetic hydrocarbon generation, is between 103 and 107 degrees C.", publisher = "Polish Geological Soc, Krakow", journal = "Annales Societatis Geologorum Poloniae", title = "Organic Geochemical Study of the Lower Miocene Kremna Basin, Serbia", volume = "84", number = "3", pages = "185-212", url = "https://hdl.handle.net/21.15107/rcub_cherry_1645" }
Perunović, T., Stojanović, K. A., Simić, V., Kašanin-Grubin, M., Šajnović, A., Eric, V., Schwarzbauer, J., Vasić, N., Jovančićević, B.,& Brčeski, I.. (2014). Organic Geochemical Study of the Lower Miocene Kremna Basin, Serbia. in Annales Societatis Geologorum Poloniae Polish Geological Soc, Krakow., 84(3), 185-212. https://hdl.handle.net/21.15107/rcub_cherry_1645
Perunović T, Stojanović KA, Simić V, Kašanin-Grubin M, Šajnović A, Eric V, Schwarzbauer J, Vasić N, Jovančićević B, Brčeski I. Organic Geochemical Study of the Lower Miocene Kremna Basin, Serbia. in Annales Societatis Geologorum Poloniae. 2014;84(3):185-212. https://hdl.handle.net/21.15107/rcub_cherry_1645 .
Perunović, Tamara, Stojanović, Ksenija A., Simić, Vladimir, Kašanin-Grubin, Milica, Šajnović, Aleksandra, Eric, Vladisav, Schwarzbauer, Jan, Vasić, Nebojša, Jovančićević, Branimir, Brčeski, Ilija, "Organic Geochemical Study of the Lower Miocene Kremna Basin, Serbia" in Annales Societatis Geologorum Poloniae, 84, no. 3 (2014):185-212, https://hdl.handle.net/21.15107/rcub_cherry_1645 .