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dc.creatorTasić, Gordana
dc.creatorMaslak, Veselin
dc.creatorHusinec, Suren
dc.creatorTodorović, Nina
dc.creatorSavić, Vladimir
dc.date.accessioned2018-11-22T00:31:18Z
dc.date.available2018-11-22T00:31:18Z
dc.date.issued2015
dc.identifier.issn0040-4039
dc.identifier.urihttp://cherry.chem.bg.ac.rs/handle/123456789/1700
dc.description.abstractThe intramolecular Heck reaction has been examined for the preparation of the core bicyclic structure of corialstonidine. Initial attempts to cyclise a vinyl iodide moiety onto a cyclic allyl alcohol were complicated by various side reactions. However, the corresponding process performed under reductive conditions on a conjugated ketone, obtained from the cyclic allyl alcohol, afforded the desired bicyclo[3.2.1] derivative. This compound possesses the skeletal features of the carbocyclic fragment of corialstonidine and is suitable for further transformations aimed towards the synthesis of the natural product or its derivatives. (C) 2015 Elsevier Ltd. All rights reserved.en
dc.publisherPergamon-Elsevier Science Ltd, Oxford
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172009/RS//
dc.rightsrestrictedAccess
dc.sourceTetrahedron Letters
dc.subjectHeck reactionen
dc.subjectCorialstonidineen
dc.subjectBicyclic ketoneen
dc.titleStudy of the intramolecular Heck reaction: synthesis of the bicyclic core of corialstonidineen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractХусинец, Сурен; Маслак, Веселин; Савиц, Владимир; Тодоровиц, Нина; Тасиц, Гордана;
dc.citation.volume56
dc.citation.issue19
dc.citation.spage2529
dc.citation.epage2532
dc.identifier.wos000353751000035
dc.identifier.doi10.1016/j.tetlet.2015.03.129
dc.citation.other56(19): 2529-2532
dc.citation.rankM22
dc.description.otherSupplementary material: [http://cherry.chem.bg.ac.rs/handle/123456789/3432]
dc.type.versionpublishedVersionen
dc.identifier.scopus2-s2.0-84937762963
dc.identifier.rcubKon_2846


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