Challenges in assignment of orbital populations in a high spin manganese(III) complex
Само за регистроване кориснике
2016
Аутори
Fitzpatrick, Anthony J.Stepanović, Stepan
Mueller-Bunz, Helge
Gruden-Pavlović, Maja
Garcia-Fernandez, Pablo
Morgan, Grace G.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Magnetic, structural and computational data of four complex salts with the same mononuclear high spin octahedral Mn(III) complex cation are reported. The manifestation of Jahn-Teller-like distortions in the Mn(III) cation is dependent on the nature of the charge-balancing anion, with small anions yielding a planar elongation and large anions freezing out a preferential axial elongation along one of the amine-Mn-imine directions within that same plane. Modulation of the lattice by changing the charge balancing anion results in mixing of the orbital symmetry due to vibrational perturbation.
Извор:
Dalton Transactions, 2016, 45, 15, 6702-6708Издавач:
- Royal Soc Chemistry, Cambridge
Финансирање / пројекти:
- Рационални дизајн и синтеза биолошки активних и координационих једињења и функционалних материјала, релевантних у (био)нанотехнологији (RS-MESTD-Basic Research (BR or ON)-172035)
- COST Action [CM1305]
- Ramon y Cajal fellowship [RYC-2013-12515]
- Cultural Service of the French Embassy in Ireland
- Science Foundation Ireland [12/IP/1703]
- Irish Higher Education Authority
- National University of Ireland
- University College Dublin
Напомена:
- Peer-reviewed manuscript: http://cherry.chem.bg.ac.rs/handle/123456789/3395
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3396
DOI: 10.1039/c5dt03914b
ISSN: 1477-9226
PubMed: 26974518
WoS: 000373994800044
Scopus: 2-s2.0-84964680292
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Fitzpatrick, Anthony J. AU - Stepanović, Stepan AU - Mueller-Bunz, Helge AU - Gruden-Pavlović, Maja AU - Garcia-Fernandez, Pablo AU - Morgan, Grace G. PY - 2016 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1912 AB - Magnetic, structural and computational data of four complex salts with the same mononuclear high spin octahedral Mn(III) complex cation are reported. The manifestation of Jahn-Teller-like distortions in the Mn(III) cation is dependent on the nature of the charge-balancing anion, with small anions yielding a planar elongation and large anions freezing out a preferential axial elongation along one of the amine-Mn-imine directions within that same plane. Modulation of the lattice by changing the charge balancing anion results in mixing of the orbital symmetry due to vibrational perturbation. PB - Royal Soc Chemistry, Cambridge T2 - Dalton Transactions T1 - Challenges in assignment of orbital populations in a high spin manganese(III) complex VL - 45 IS - 15 SP - 6702 EP - 6708 DO - 10.1039/c5dt03914b ER -
@article{ author = "Fitzpatrick, Anthony J. and Stepanović, Stepan and Mueller-Bunz, Helge and Gruden-Pavlović, Maja and Garcia-Fernandez, Pablo and Morgan, Grace G.", year = "2016", abstract = "Magnetic, structural and computational data of four complex salts with the same mononuclear high spin octahedral Mn(III) complex cation are reported. The manifestation of Jahn-Teller-like distortions in the Mn(III) cation is dependent on the nature of the charge-balancing anion, with small anions yielding a planar elongation and large anions freezing out a preferential axial elongation along one of the amine-Mn-imine directions within that same plane. Modulation of the lattice by changing the charge balancing anion results in mixing of the orbital symmetry due to vibrational perturbation.", publisher = "Royal Soc Chemistry, Cambridge", journal = "Dalton Transactions", title = "Challenges in assignment of orbital populations in a high spin manganese(III) complex", volume = "45", number = "15", pages = "6702-6708", doi = "10.1039/c5dt03914b" }
Fitzpatrick, A. J., Stepanović, S., Mueller-Bunz, H., Gruden-Pavlović, M., Garcia-Fernandez, P.,& Morgan, G. G.. (2016). Challenges in assignment of orbital populations in a high spin manganese(III) complex. in Dalton Transactions Royal Soc Chemistry, Cambridge., 45(15), 6702-6708. https://doi.org/10.1039/c5dt03914b
Fitzpatrick AJ, Stepanović S, Mueller-Bunz H, Gruden-Pavlović M, Garcia-Fernandez P, Morgan GG. Challenges in assignment of orbital populations in a high spin manganese(III) complex. in Dalton Transactions. 2016;45(15):6702-6708. doi:10.1039/c5dt03914b .
Fitzpatrick, Anthony J., Stepanović, Stepan, Mueller-Bunz, Helge, Gruden-Pavlović, Maja, Garcia-Fernandez, Pablo, Morgan, Grace G., "Challenges in assignment of orbital populations in a high spin manganese(III) complex" in Dalton Transactions, 45, no. 15 (2016):6702-6708, https://doi.org/10.1039/c5dt03914b . .