Challenges in assignment of orbital populations in a high spin manganese(III) complex
Samo za registrovane korisnike
2016
Autori
Fitzpatrick, A. J.Stepanovic, S.
Mueller-Bunz, H.
Gruden-Pavlović, Maja

Garcia-Fernandez, P.
Morgan, G. G.
Članak u časopisu (Objavljena verzija)

Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Magnetic, structural and computational data of four complex salts with the same mononuclear high spin octahedral Mn(III) complex cation are reported. The manifestation of Jahn-Teller-like distortions in the Mn(III) cation is dependent on the nature of the charge-balancing anion, with small anions yielding a planar elongation and large anions freezing out a preferential axial elongation along one of the amine-Mn-imine directions within that same plane. Modulation of the lattice by changing the charge balancing anion results in mixing of the orbital symmetry due to vibrational perturbation.
Izvor:
Dalton Transactions, 2016, 45, 15, 6702-6708Izdavač:
- Royal Soc Chemistry, Cambridge
Projekti:
- Racionalni dizajn i sinteza biološki aktivnih i koordinacionih jedinjenja i funkcionalnih materijala, relevantnih u (bio)nanotehnologiji (RS-172035)
- COST Action [CM1305]
- Ramon y Cajal fellowship [RYC-2013-12515]
- Cultural Service of the French Embassy in Ireland
- Science Foundation Ireland [12/IP/1703]
- Irish Higher Education Authority
- National University of Ireland
- University College Dublin
DOI: 10.1039/c5dt03914b
ISSN: 1477-9226
PubMed: 26974518