Show simple item record

Eksperimentalni i teorijski dokazi da je Cu(II) jon u vodenom rastvoru pentakoordinovan

dc.creatorMedaković, Vesna
dc.creatorZarić, Snežana
dc.date.accessioned2018-11-22T00:03:40Z
dc.date.available2018-11-22T00:03:40Z
dc.date.issued2001
dc.identifier.issn0440-6826
dc.identifier.urihttp://cherry.chem.bg.ac.rs/handle/123456789/248
dc.description.abstractThe structure of the hydrated Cu(II) complex was determined by both neutron diffraction and first-principles molecular dynamics. In contrast with the generally accepted picture, which assumes an octahedrally solvated Cu(II) ion, new experimental and theoretical results favor fivefold coordination. The simulation reveals that the solvated complex undergoes frequent transformations between square pyramidal and trigonal bipyramidal configurations. The preference of the Cu(II) ion for fivefold instead of six fold coordination, which occurs for other cations of comparable charge and size, results from Jahn-Teller destabilization of the octahedral complex.en
dc.rightsopenAccess
dc.sourceHemijski pregled
dc.titleFirst solvation shell of the Cu(II) aqua ion: Evidence fore five-fold coordinationen
dc.titleEksperimentalni i teorijski dokazi da je Cu(II) jon u vodenom rastvoru pentakoordinovansr
dc.typearticle
dc.rights.licenseARR
dcterms.abstractЗарић, Снежана; Медаковић, Весна; Експериментални и теоријски докази да је Цу(ИИ) јон у воденом раствору пентакоординован; Експериментални и теоријски докази да је Цу(ИИ) јон у воденом раствору пентакоординован;
dc.citation.volume42
dc.citation.issue6
dc.citation.spage122
dc.citation.epage124
dc.citation.other42(6): 122-124
dc.type.versionpublishedVersion
dc.identifier.rcubKon_464


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record