Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard’s T hydrazone complex
Autori
Čobeljić, BožidarPevec, Andrej
Jagličić, Zvonko
Milenković, Milica R.
Turel, Iztok
Radanović, Dušanka D.
Milenković, Marina
Anđelković, Katarina K.
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The isothiocyanato Fe(III) complex with (E)-N,N,N-trimethyl-2-oxo--2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs.
Ključne reči:
Hydrazone / Pseudohalides / X-ray structure, magnetic propertiesIzvor:
Journal of the Serbian Chemical Society, 2018, 83, 12, 1327-1337Finansiranje / projekti:
- Interakcije prirodnih proizvoda, njihovih derivata i kompleksnih jedinjenja sa proteinima i nukleinskim kiselinama (RS-MESTD-Basic Research (BR or ON)-172055)
Napomena:
- Supplamantary material: http://cherry.chem.bg.ac.rs/handle/123456789/3307
DOI: 10.2298/JSC180828079C
ISSN: 0352-5139
WoS: 000454508900004
Scopus: 2-s2.0-85059303962
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Čobeljić, Božidar AU - Pevec, Andrej AU - Jagličić, Zvonko AU - Milenković, Milica R. AU - Turel, Iztok AU - Radanović, Dušanka D. AU - Milenković, Marina AU - Anđelković, Katarina K. PY - 2018 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2810 AB - The isothiocyanato Fe(III) complex with (E)-N,N,N-trimethyl-2-oxo--2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs. T2 - Journal of the Serbian Chemical Society T1 - Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard’s T hydrazone complex VL - 83 IS - 12 SP - 1327 EP - 1337 DO - 10.2298/JSC180828079C ER -
@article{ author = "Čobeljić, Božidar and Pevec, Andrej and Jagličić, Zvonko and Milenković, Milica R. and Turel, Iztok and Radanović, Dušanka D. and Milenković, Marina and Anđelković, Katarina K.", year = "2018", abstract = "The isothiocyanato Fe(III) complex with (E)-N,N,N-trimethyl-2-oxo--2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs.", journal = "Journal of the Serbian Chemical Society", title = "Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard’s T hydrazone complex", volume = "83", number = "12", pages = "1327-1337", doi = "10.2298/JSC180828079C" }
Čobeljić, B., Pevec, A., Jagličić, Z., Milenković, M. R., Turel, I., Radanović, D. D., Milenković, M.,& Anđelković, K. K.. (2018). Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard’s T hydrazone complex. in Journal of the Serbian Chemical Society, 83(12), 1327-1337. https://doi.org/10.2298/JSC180828079C
Čobeljić B, Pevec A, Jagličić Z, Milenković MR, Turel I, Radanović DD, Milenković M, Anđelković KK. Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard’s T hydrazone complex. in Journal of the Serbian Chemical Society. 2018;83(12):1327-1337. doi:10.2298/JSC180828079C .
Čobeljić, Božidar, Pevec, Andrej, Jagličić, Zvonko, Milenković, Milica R., Turel, Iztok, Radanović, Dušanka D., Milenković, Marina, Anđelković, Katarina K., "Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard’s T hydrazone complex" in Journal of the Serbian Chemical Society, 83, no. 12 (2018):1327-1337, https://doi.org/10.2298/JSC180828079C . .