Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand
Само за регистроване кориснике
2019
Аутори
Perić, MarkoKyne, Sara H.
Gruden, Maja
Rodić, Marko
Jeremić, Dejan
Stanković, Dalibor
Brčeski, Ilija
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic.
Кључне речи:
Binuclear complex / Density functional theory / Magnetic properties / X-ray structure determinationИзвор:
Monatshefte fur Chemie, 2019, 150, 7, 1241-1248Издавач:
- Springer-Verlag GmbH Austria
Финансирање / пројекти:
- Рационални дизајн и синтеза биолошки активних и координационих једињења и функционалних материјала, релевантних у (био)нанотехнологији (RS-MESTD-Basic Research (BR or ON)-172035)
- Корелација структуре и особина природних и синтетичких молекула и њихових комплекса са металима (RS-MESTD-Basic Research (BR or ON)-172017)
- Magbiovin project (FP7-ERAChairs-Pilot Call-2013, Grant agreement: 621375)
Напомена:
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3317
DOI: 10.1007/s00706-019-02405-7
ISSN: 0026-9247
WoS: 000475674200009
Scopus: 2-s2.0-85068563687
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Perić, Marko AU - Kyne, Sara H. AU - Gruden, Maja AU - Rodić, Marko AU - Jeremić, Dejan AU - Stanković, Dalibor AU - Brčeski, Ilija PY - 2019 UR - https://cherry.chem.bg.ac.rs/handle/123456789/3316 AB - In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic. PB - Springer-Verlag GmbH Austria T2 - Monatshefte fur Chemie T1 - Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand VL - 150 IS - 7 SP - 1241 EP - 1248 DO - 10.1007/s00706-019-02405-7 ER -
@article{ author = "Perić, Marko and Kyne, Sara H. and Gruden, Maja and Rodić, Marko and Jeremić, Dejan and Stanković, Dalibor and Brčeski, Ilija", year = "2019", abstract = "In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic.", publisher = "Springer-Verlag GmbH Austria", journal = "Monatshefte fur Chemie", title = "Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand", volume = "150", number = "7", pages = "1241-1248", doi = "10.1007/s00706-019-02405-7" }
Perić, M., Kyne, S. H., Gruden, M., Rodić, M., Jeremić, D., Stanković, D.,& Brčeski, I.. (2019). Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand. in Monatshefte fur Chemie Springer-Verlag GmbH Austria., 150(7), 1241-1248. https://doi.org/10.1007/s00706-019-02405-7
Perić M, Kyne SH, Gruden M, Rodić M, Jeremić D, Stanković D, Brčeski I. Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand. in Monatshefte fur Chemie. 2019;150(7):1241-1248. doi:10.1007/s00706-019-02405-7 .
Perić, Marko, Kyne, Sara H., Gruden, Maja, Rodić, Marko, Jeremić, Dejan, Stanković, Dalibor, Brčeski, Ilija, "Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand" in Monatshefte fur Chemie, 150, no. 7 (2019):1241-1248, https://doi.org/10.1007/s00706-019-02405-7 . .