Приказ основних података о документу
Soft Templating and Disorder in an Applied 1D Cobalt Coordination Polymer Electrocatalyst
dc.creator | Petrović, Predrag | |
dc.creator | Goberna Ferrón, Sara | |
dc.creator | Stanley, George | |
dc.creator | Zarić, Snežana D. | |
dc.creator | Fox, Thomas | |
dc.creator | Brothers, Edward N. | |
dc.creator | Sheehan, Stafford W. | |
dc.creator | Anastas, Paul T. | |
dc.creator | Patzke, Greta R. | |
dc.creator | Bloomfield, Aaron J. | |
dc.creator | Mooré, René | |
dc.creator | Triana, C.A. | |
dc.date.accessioned | 2020-02-05T09:53:41Z | |
dc.date.available | 2020-02-05T09:53:41Z | |
dc.date.issued | 2019 | |
dc.identifier.issn | 2590-2393 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/3831 | |
dc.description.abstract | Disordered materials with resilient and soft-templated functional units bear the potential to fill the pipeline of robust catalysts for renewable energy storage. However, for novel materials lacking long-range order, the ability to discern local structure with atomic resolution still pushes the boundaries of current analytical and modeling approaches. We introduce a two-pillar strategy to monitor the formation and unravel the structure of the first disordered onedimensional cobalt coordination polymer catalyst, Co-dppeO2. This target material excels through proven high performance in commercial alkaline electrolyzers and organic transformations. We demonstrate that the key architecture behind this activity is the unconventional embedding of hydrated {H2O-Co2(OH)2-OH2} edge-site motifs, nested into a flexible organic matrix of highly oxidized and bridging hydrophobic dppeO2 ligands. Our combination of in situ spectroscopy and computational modeling of X-ray scattering and absorption spectra, backed with complementary experimental techniques, holds the key to understanding the atomic-range structure of important disordered materials. | |
dc.publisher | Cell Press | |
dc.relation | University of Zurich, Switzerland, and the University Research Priority Program (URPP) for Solar Light to Chemical Energy Conversion (LightChEC). | |
dc.relation | Swiss National Science Foundation, Switzerland (Sinergia grant no. CRSII2_160801/1). | |
dc.relation | Qatar National Research Foundation, Qatar, under NPRP10-0125-170246. | |
dc.rights | openAccess | |
dc.source | Matter | |
dc.subject | cobalt catalysts | |
dc.subject | coordination polymers | |
dc.subject | electrocatalysts | |
dc.subject | energy materials | |
dc.subject | hybrid materials | |
dc.subject | oxygen evolution reaction | |
dc.subject | pair distribution function | |
dc.subject | phosphine oxides | |
dc.subject | water oxidation | |
dc.subject | X-ray absorption spectroscopy | |
dc.title | Soft Templating and Disorder in an Applied 1D Cobalt Coordination Polymer Electrocatalyst | |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Петровић, Предраг; Триана, Ц.A.; Зарић, Снежана; Гоберна Феррóн, Сара; Моорé, Ренé; Фоx, Тхомас; Бротхерс, Едwард Н.; Схеехан, Стаффорд W.; Aнастас, Паул Т.; Патзке, Грета Р.; Блоомфиелд, Aарон Ј.; Станлеy, Георге; | |
dc.citation.volume | 1 | |
dc.citation.issue | 5 | |
dc.citation.spage | 1354 | |
dc.citation.epage | 1369 | |
dc.identifier.wos | 000519846700027 | |
dc.identifier.doi | 10.1016/j.matt.2019.06.021 | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-85078439511 | |
dc.identifier.fulltext | https://cherry.chem.bg.ac.rs/bitstream/id/16628/Soft_Templating_and_pub_2019.pdf |