Sequential free radical reactions with xanthates: Cyclopentane ring annulation
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In the presence of electron-rich alkenes, electro- and ambiphilic homoallylic radicals, generated by homolytic decomposition of the corresponding xanthates, undergo annulation with inverse electron-demand, and afford cyclopentane derivatives in moderate to good yields.
Keywords:radicals / annulations / xanthates / cyclopentane
Source:Synlett, 1998, 12, 1435-1437
- Georg Thieme Verlag, Stuttgart