One-pot combustion synthesis of nickel oxide and hematite: From simple coordination compounds to high purity metal oxide nanoparticles
Аутори
Jeremić, DejanAnđelković, Ljubica
Milenković, Milica R.
Šuljagić, Marija
Šumar-Ristović, Maja
Ostojić, Sanja B.
Nikolić, Aleksandar S.
Vulić, Predrag J.
Brčeski, Ilija
Pavlović, Vladimir B.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
This work is the first report of a very simple and fast one-pot synthesis of nickel oxide (NiO) and hematite (α-Fe2O3) nanoparticles by thermal decomposition of transition metal aqua complexes with camphor sulfonate anions. Obtained nanopowders were characterized by X-ray powder diffraction, Fourier transform IR analysis, scanning electron microscopy, and Energy-dispersive X-ray spectroscopy. X-ray powder diffraction confirmed the formation of high purity NiO and α-Fe2O3 crystal phases. In the case of α-Fe2O3, about five times larger average crystallite size was obtained. Fourier transform IR spectra of synthesized materials showed characteristic peaks for NiO and α-Fe2O3 nanostructures. To visualize the morphology and the chemical composition of the final products Scanning electron microscopy and Energy-dispersive X-ray spectroscopy were performed. The thermogravimetric analysis was done for a better understanding of the general thermal behavior of precursor compounds. This easy-to-pe...rform and fast preparation method opens a broad range of obtained materials’ usage, particularly due to its economic viability
Кључне речи:
Nanomaterials / Nickel oxide / Hematite / camphor sulfonates / One-pot synthesisИзвор:
Science of Sintering, 2020, 52, 4, 481-490Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200026 (Универзитет у Београду, Институт за хемију, технологију и металургију - ИХТМ) (RS-MESTD-inst-2020-200026)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200168 (Универзитет у Београду, Хемијски факултет) (RS-MESTD-inst-2020-200168)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200168 (Универзитет у Београду, Хемијски факултет) (RS-MESTD-inst-2020-200168)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200116 (Универзитет у Београду, Пољопривредни факултет) (RS-MESTD-inst-2020-200116)
DOI: 10.2298/SOS2004481J
ISSN: 0350-820X
WoS: 000600505000009
Scopus: 2-s2.0-85098651318
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Jeremić, Dejan AU - Anđelković, Ljubica AU - Milenković, Milica R. AU - Šuljagić, Marija AU - Šumar-Ristović, Maja AU - Ostojić, Sanja B. AU - Nikolić, Aleksandar S. AU - Vulić, Predrag J. AU - Brčeski, Ilija AU - Pavlović, Vladimir B. PY - 2020 UR - https://cherry.chem.bg.ac.rs/handle/123456789/4306 AB - This work is the first report of a very simple and fast one-pot synthesis of nickel oxide (NiO) and hematite (α-Fe2O3) nanoparticles by thermal decomposition of transition metal aqua complexes with camphor sulfonate anions. Obtained nanopowders were characterized by X-ray powder diffraction, Fourier transform IR analysis, scanning electron microscopy, and Energy-dispersive X-ray spectroscopy. X-ray powder diffraction confirmed the formation of high purity NiO and α-Fe2O3 crystal phases. In the case of α-Fe2O3, about five times larger average crystallite size was obtained. Fourier transform IR spectra of synthesized materials showed characteristic peaks for NiO and α-Fe2O3 nanostructures. To visualize the morphology and the chemical composition of the final products Scanning electron microscopy and Energy-dispersive X-ray spectroscopy were performed. The thermogravimetric analysis was done for a better understanding of the general thermal behavior of precursor compounds. This easy-to-perform and fast preparation method opens a broad range of obtained materials’ usage, particularly due to its economic viability T2 - Science of Sintering T1 - One-pot combustion synthesis of nickel oxide and hematite: From simple coordination compounds to high purity metal oxide nanoparticles VL - 52 IS - 4 SP - 481 EP - 490 DO - 10.2298/SOS2004481J ER -
@article{ author = "Jeremić, Dejan and Anđelković, Ljubica and Milenković, Milica R. and Šuljagić, Marija and Šumar-Ristović, Maja and Ostojić, Sanja B. and Nikolić, Aleksandar S. and Vulić, Predrag J. and Brčeski, Ilija and Pavlović, Vladimir B.", year = "2020", abstract = "This work is the first report of a very simple and fast one-pot synthesis of nickel oxide (NiO) and hematite (α-Fe2O3) nanoparticles by thermal decomposition of transition metal aqua complexes with camphor sulfonate anions. Obtained nanopowders were characterized by X-ray powder diffraction, Fourier transform IR analysis, scanning electron microscopy, and Energy-dispersive X-ray spectroscopy. X-ray powder diffraction confirmed the formation of high purity NiO and α-Fe2O3 crystal phases. In the case of α-Fe2O3, about five times larger average crystallite size was obtained. Fourier transform IR spectra of synthesized materials showed characteristic peaks for NiO and α-Fe2O3 nanostructures. To visualize the morphology and the chemical composition of the final products Scanning electron microscopy and Energy-dispersive X-ray spectroscopy were performed. The thermogravimetric analysis was done for a better understanding of the general thermal behavior of precursor compounds. This easy-to-perform and fast preparation method opens a broad range of obtained materials’ usage, particularly due to its economic viability", journal = "Science of Sintering", title = "One-pot combustion synthesis of nickel oxide and hematite: From simple coordination compounds to high purity metal oxide nanoparticles", volume = "52", number = "4", pages = "481-490", doi = "10.2298/SOS2004481J" }
Jeremić, D., Anđelković, L., Milenković, M. R., Šuljagić, M., Šumar-Ristović, M., Ostojić, S. B., Nikolić, A. S., Vulić, P. J., Brčeski, I.,& Pavlović, V. B.. (2020). One-pot combustion synthesis of nickel oxide and hematite: From simple coordination compounds to high purity metal oxide nanoparticles. in Science of Sintering, 52(4), 481-490. https://doi.org/10.2298/SOS2004481J
Jeremić D, Anđelković L, Milenković MR, Šuljagić M, Šumar-Ristović M, Ostojić SB, Nikolić AS, Vulić PJ, Brčeski I, Pavlović VB. One-pot combustion synthesis of nickel oxide and hematite: From simple coordination compounds to high purity metal oxide nanoparticles. in Science of Sintering. 2020;52(4):481-490. doi:10.2298/SOS2004481J .
Jeremić, Dejan, Anđelković, Ljubica, Milenković, Milica R., Šuljagić, Marija, Šumar-Ristović, Maja, Ostojić, Sanja B., Nikolić, Aleksandar S., Vulić, Predrag J., Brčeski, Ilija, Pavlović, Vladimir B., "One-pot combustion synthesis of nickel oxide and hematite: From simple coordination compounds to high purity metal oxide nanoparticles" in Science of Sintering, 52, no. 4 (2020):481-490, https://doi.org/10.2298/SOS2004481J . .