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Sinteza i karakterizacija uns-cis-(etilendiamin-N,N'-di-3-propionato) (N-alkiletilendiamin) kobalt(III) kompleksa

dc.creatorSabo, Tibor
dc.creatorGrgurić-Šipka, Sanja
dc.date.accessioned2018-11-22T00:03:09Z
dc.date.available2018-11-22T00:03:09Z
dc.date.issued2000
dc.identifier.issn0352-5139
dc.identifier.urihttp://cherry.chem.bg.ac.rs/handle/123456789/431
dc.description.abstractThree octahedral cobalt(III) complexes of the general formula uns-cis-[Co(eddp)(R-en)]Cl . H2O, where eddp = the tetradentate ONNO-type ligand ethylenediamine-N,N'-di-3-propionate and R-en = a bidentate NN-type ligand, either N-methyl, N-ethyl or N-iso-propylethylenediamine. The complexes were prepared by the reaction of sodium uns-cis-(ethylenediamine-N,N'-di-3-propionato)(carbonato)cobalt(III)dihydrate with the corresponding diamine. They were isolated chromatographically and characterized by elemental analysis, infrared and electronic absorption spectroscopy.en
dc.description.abstractU ovom radu su sintetisana i okarakterisana tri oktaedarska kobalt(III) kompleksa opšte formule uns-cis-[Co(eddp) (R-en)]Cl∙2H2O, gde je eddp tetradentatni ONNO- tip liganda etilendiamin-N,N'-di-3-propionat, a R-en bidentatni NN ligand, N-metil, N-etil ili N-izopropiletilendidamin. Kompleksi su sintetisani polazeći od uns-cis- natrijum(etilendiamin-N,N'-di-3-propionato)(karbonato)kobaltat(III)-dihidrata i odgovarajućih diamina, izolovani hromatografski i okarakterisani elementalnom analizom, infracrvenom i elektronsko-apsorpcionom spektroskopijom.sr
dc.publisherSerbian Chemical Soc, Belgrade
dc.rightsopenAccess
dc.sourceJournal of the Serbian Chemical Society
dc.subjectcobalt(III) complexesen
dc.subjectethylenediamine-N,N '-di-3-propionic aciden
dc.subjectethylenediamine-N,N'-di-3-propionic aciden
dc.subjectN-alkylethylenediaminesen
dc.subjectN-alkylethylenediaminesen
dc.titleThe preparation and characterization of uns-cis-(ethylenediamine-N,N '-di-3-propionato)(N-alkylethylene diamines)cobalt(III) complexesen
dc.titleSinteza i karakterizacija uns-cis-(etilendiamin-N,N'-di-3-propionato) (N-alkiletilendiamin) kobalt(III) kompleksasr
dc.typearticle
dc.rights.licenseBY-NC-ND
dcterms.abstractСабо, Тибор; Гргурић-Шипка, Сања; Синтеза и карактеризација унс-цис-(етилендиамин-Н,Н'-ди-3-пропионато) (Н-алкилетилендиамин) кобалт(ИИИ) комплекса; Синтеза и карактеризација унс-цис-(етилендиамин-Н,Н'-ди-3-пропионато) (Н-алкилетилендиамин) кобалт(ИИИ) комплекса;
dc.citation.volume65
dc.citation.issue3
dc.citation.spage167
dc.citation.epage171
dc.identifier.wos000086052500003
dc.citation.other65(3): 167-171
dc.citation.rankM23
dc.type.versionpublishedVersion
dc.identifier.scopus2-s2.0-0034402512
dc.identifier.fulltexthttp://cherry.chem.bg.ac.rs/bitstream/id/9749/429.pdf
dc.identifier.rcubKon_1405


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