The mechanisms of tris(4-morpholinecarbodithioato-S,S′)cobalt(III) complex formation by solid state reaction from ammine cobalt(III) complexes
Апстракт
In this paper, the solid state reaction, conducted with a mixture of pentaamminechlorocobalt(III) chloride and potassium 4-morpholinecarbodithioate was investigated under isothermal conditions. The reaction proceeds at relatively low temperatures (154-192 °C). The yield of product solid-solid reaction, tris(4-morpholinecarbodithioato-S,S')cobalt(III) complex, does not exceed 65%. The kinetic of the reaction of powdered and pressed samples were investigated. The reaction proceeded according to the diffusional mechanism. Activation energies of 200 kJ/mol and 100 kJ/mol for the powdered and pressed form, respectively, were obtained.
Кључне речи:
Cobalt(III) complexes / Kinetic / Mechanism / Pentaamminechlorocobalt(III) chloride / Potassium 4-morpholinecarbodithioateИзвор:
Journal of the Serbian Chemical Society, 1997, 62, 11, 1037-1044Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Sabo, Tibor AU - Vlajković, J. AU - Dondur, V. PY - 1997 UR - https://cherry.chem.bg.ac.rs/handle/123456789/46 AB - In this paper, the solid state reaction, conducted with a mixture of pentaamminechlorocobalt(III) chloride and potassium 4-morpholinecarbodithioate was investigated under isothermal conditions. The reaction proceeds at relatively low temperatures (154-192 °C). The yield of product solid-solid reaction, tris(4-morpholinecarbodithioato-S,S')cobalt(III) complex, does not exceed 65%. The kinetic of the reaction of powdered and pressed samples were investigated. The reaction proceeded according to the diffusional mechanism. Activation energies of 200 kJ/mol and 100 kJ/mol for the powdered and pressed form, respectively, were obtained. T2 - Journal of the Serbian Chemical Society T1 - The mechanisms of tris(4-morpholinecarbodithioato-S,S′)cobalt(III) complex formation by solid state reaction from ammine cobalt(III) complexes VL - 62 IS - 11 SP - 1037 EP - 1044 UR - https://hdl.handle.net/21.15107/rcub_cherry_46 ER -
@article{ author = "Sabo, Tibor and Vlajković, J. and Dondur, V.", year = "1997", abstract = "In this paper, the solid state reaction, conducted with a mixture of pentaamminechlorocobalt(III) chloride and potassium 4-morpholinecarbodithioate was investigated under isothermal conditions. The reaction proceeds at relatively low temperatures (154-192 °C). The yield of product solid-solid reaction, tris(4-morpholinecarbodithioato-S,S')cobalt(III) complex, does not exceed 65%. The kinetic of the reaction of powdered and pressed samples were investigated. The reaction proceeded according to the diffusional mechanism. Activation energies of 200 kJ/mol and 100 kJ/mol for the powdered and pressed form, respectively, were obtained.", journal = "Journal of the Serbian Chemical Society", title = "The mechanisms of tris(4-morpholinecarbodithioato-S,S′)cobalt(III) complex formation by solid state reaction from ammine cobalt(III) complexes", volume = "62", number = "11", pages = "1037-1044", url = "https://hdl.handle.net/21.15107/rcub_cherry_46" }
Sabo, T., Vlajković, J.,& Dondur, V.. (1997). The mechanisms of tris(4-morpholinecarbodithioato-S,S′)cobalt(III) complex formation by solid state reaction from ammine cobalt(III) complexes. in Journal of the Serbian Chemical Society, 62(11), 1037-1044. https://hdl.handle.net/21.15107/rcub_cherry_46
Sabo T, Vlajković J, Dondur V. The mechanisms of tris(4-morpholinecarbodithioato-S,S′)cobalt(III) complex formation by solid state reaction from ammine cobalt(III) complexes. in Journal of the Serbian Chemical Society. 1997;62(11):1037-1044. https://hdl.handle.net/21.15107/rcub_cherry_46 .
Sabo, Tibor, Vlajković, J., Dondur, V., "The mechanisms of tris(4-morpholinecarbodithioato-S,S′)cobalt(III) complex formation by solid state reaction from ammine cobalt(III) complexes" in Journal of the Serbian Chemical Society, 62, no. 11 (1997):1037-1044, https://hdl.handle.net/21.15107/rcub_cherry_46 .