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Free radical domino reactions in the synthesis of small ring compounds: multiple annulation of cyclopropane-containing polycycles
dc.creator | Ferjančić, Zorana | |
dc.creator | Čeković, Živorad | |
dc.creator | Saičić, Radomir | |
dc.date.accessioned | 2018-11-22T00:04:03Z | |
dc.date.available | 2018-11-22T00:04:03Z | |
dc.date.issued | 2001 | |
dc.identifier.issn | 1387-1609 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/470 | |
dc.description.abstract | Free radical approach to fused vinylcyclopropane derivatives is described. Homolytic decomposition of Barton esters 4a-f in the presence of activated alkynes affords bicyclo[3.1.0]hex-2-ene derivatives 5a-g in moderate yields (18-52 %). The propagation sequence comprises: intermolecular addition/5-exo-cyclization/3-exo-cyclization/beta -elimination, and allows for a one-pot synthesis of bicyclic cyclopropane derivatives starting from two acyclic, unsaturated compounds. (C) 2001 Academie des sciences / Editions scientifiques et medicales Elsevier SAS. | en |
dc.publisher | Editions Scientifiques Medicales Elsevier, Paris Cedex 15 | |
dc.rights | restrictedAccess | |
dc.source | Comptes Rendus de L'academie des Sciences: Series IIc: Chemistry | |
dc.subject | radicals | en |
dc.subject | cyclization | en |
dc.subject | cyclopropane | en |
dc.subject | polycycles | en |
dc.subject | domino reactions | en |
dc.title | Free radical domino reactions in the synthesis of small ring compounds: multiple annulation of cyclopropane-containing polycycles | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Цековиц, З; Ферјанчић, Зорана; Саичић, Радомир; | |
dc.citation.volume | 4 | |
dc.citation.issue | 7 | |
dc.citation.spage | 599 | |
dc.citation.epage | 610 | |
dc.identifier.wos | 000170832300012 | |
dc.identifier.doi | 10.1016/S1387-1609(01)01276-2 | |
dc.citation.other | 4(7): 599-610 | |
dc.citation.rank | M23 | |
dc.type.version | publishedVersion | en |
dc.identifier.scopus | 2-s2.0-18044403837 |