Mechanism of stereoselective synthesis of push-pull (2)-4-oxothiazolidine derivatives containing an exocyclic double bond. A MNDO-PM3 Study
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Calculations using the MNDO-PM3 method were performed to elucidate the mechanism of stereoselective base-catalyzed reaction affording exclusively (2)-2-alkylidene-4-oxothiazolidine push-pull derivatives from the corresponding a-mercapto esters and activated beta-oxonitriles in ethanol as a solvent.
Keywords:MNDO-PM3 / Z-2-alkylidene-4-oxothiazolidine
Source:Journal of Chemical Research, 2002, 10, 485-489
- Science Reviews 2000 Ltd, St Albans