Regioselective free radical phenylsulfenation of a non-activated delta-carbon atom by the photolysis of alkyl benzenesulfenate
Само за регистроване кориснике
2003
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
A regioselective free radical introduction of a phenylthio group onto a non-activated delta-carbon atom was achieved by photolysis of alkyl benzenesulfenates in the presence of hexabutylditin, and delta-phenylthio alcohols were obtained in 35-91% yields. delta-Phenylsulfenylation of a non-activated carbon atom induced only by irradiation of alkyl benzenesulfenates (without initiation by hexabutylditin) also occurs, however, slower reaction rates were observed and lower yields of delta-phenylthio alcohols were obtained. (C) 2002 Published by Elsevier Science Ltd.
Кључне речи:
radicals and radical reactions / 1,5-hydrogen migration / intramolecular fuctionalization / sulfenic acids and derivatives / sulfides / delta-phenylthio alcoholsИзвор:
Tetrahedron, 2003, 59, 2, 187-196Издавач:
- Pergamon-Elsevier Science Ltd, Oxford
DOI: 10.1016/S0040-4020(02)01477-1
ISSN: 0040-4020
WoS: 000180259400007
Scopus: 2-s2.0-0037421130
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Petrović, G. AU - Saičić, Radomir AU - Čeković, Živorad PY - 2003 UR - https://cherry.chem.bg.ac.rs/handle/123456789/532 AB - A regioselective free radical introduction of a phenylthio group onto a non-activated delta-carbon atom was achieved by photolysis of alkyl benzenesulfenates in the presence of hexabutylditin, and delta-phenylthio alcohols were obtained in 35-91% yields. delta-Phenylsulfenylation of a non-activated carbon atom induced only by irradiation of alkyl benzenesulfenates (without initiation by hexabutylditin) also occurs, however, slower reaction rates were observed and lower yields of delta-phenylthio alcohols were obtained. (C) 2002 Published by Elsevier Science Ltd. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Tetrahedron T1 - Regioselective free radical phenylsulfenation of a non-activated delta-carbon atom by the photolysis of alkyl benzenesulfenate VL - 59 IS - 2 SP - 187 EP - 196 DO - 10.1016/S0040-4020(02)01477-1 ER -
@article{ author = "Petrović, G. and Saičić, Radomir and Čeković, Živorad", year = "2003", abstract = "A regioselective free radical introduction of a phenylthio group onto a non-activated delta-carbon atom was achieved by photolysis of alkyl benzenesulfenates in the presence of hexabutylditin, and delta-phenylthio alcohols were obtained in 35-91% yields. delta-Phenylsulfenylation of a non-activated carbon atom induced only by irradiation of alkyl benzenesulfenates (without initiation by hexabutylditin) also occurs, however, slower reaction rates were observed and lower yields of delta-phenylthio alcohols were obtained. (C) 2002 Published by Elsevier Science Ltd.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Tetrahedron", title = "Regioselective free radical phenylsulfenation of a non-activated delta-carbon atom by the photolysis of alkyl benzenesulfenate", volume = "59", number = "2", pages = "187-196", doi = "10.1016/S0040-4020(02)01477-1" }
Petrović, G., Saičić, R.,& Čeković, Ž.. (2003). Regioselective free radical phenylsulfenation of a non-activated delta-carbon atom by the photolysis of alkyl benzenesulfenate. in Tetrahedron Pergamon-Elsevier Science Ltd, Oxford., 59(2), 187-196. https://doi.org/10.1016/S0040-4020(02)01477-1
Petrović G, Saičić R, Čeković Ž. Regioselective free radical phenylsulfenation of a non-activated delta-carbon atom by the photolysis of alkyl benzenesulfenate. in Tetrahedron. 2003;59(2):187-196. doi:10.1016/S0040-4020(02)01477-1 .
Petrović, G., Saičić, Radomir, Čeković, Živorad, "Regioselective free radical phenylsulfenation of a non-activated delta-carbon atom by the photolysis of alkyl benzenesulfenate" in Tetrahedron, 59, no. 2 (2003):187-196, https://doi.org/10.1016/S0040-4020(02)01477-1 . .