Heterogeneous copper-catalyzed direct reduction of C-glycosidic enones to saturated alcohols in water
Само за регистроване кориснике
2019
Аутори
Petitjean, Laurenede Winter, Tamara M.
Petrovic, Predrag V.
Coish, Philip
Hitce, Julien
Moreau, Magali
Bordier, Thierry
Erythropel, Hanno C.
Anastas, Paul T.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
We report a novel method for the reduction of α,β-unsaturated enones to the corresponding fully saturated alcohols in a single procedure. Remarkably, the method employs a heterogeneous copper catalyst in water and only requires resin-treatment for isolation of C-glycosidic alcohols as pure, diastereomeric mixtures. Our methodology was applied to the reduction of aromatic and aliphatic enones which furnished a library of C-glycosidic saturated alcohols from renewable sugars via a green and sustainable approach.
Извор:
Green Chemistry, 2019, 21, 238-Издавач:
- Royal Society of Chemistry
Колекције
Институција/група
Inovacioni centar / Innovation CentreTY - JOUR AU - Petitjean, Laurene AU - de Winter, Tamara M. AU - Petrovic, Predrag V. AU - Coish, Philip AU - Hitce, Julien AU - Moreau, Magali AU - Bordier, Thierry AU - Erythropel, Hanno C. AU - Anastas, Paul T. PY - 2019 UR - http://cherry.chem.bg.ac.rs/handle/123456789/5370 AB - We report a novel method for the reduction of α,β-unsaturated enones to the corresponding fully saturated alcohols in a single procedure. Remarkably, the method employs a heterogeneous copper catalyst in water and only requires resin-treatment for isolation of C-glycosidic alcohols as pure, diastereomeric mixtures. Our methodology was applied to the reduction of aromatic and aliphatic enones which furnished a library of C-glycosidic saturated alcohols from renewable sugars via a green and sustainable approach. PB - Royal Society of Chemistry T2 - Green Chemistry T1 - Heterogeneous copper-catalyzed direct reduction of C-glycosidic enones to saturated alcohols in water VL - 21 SP - 238 DO - 10.1039/C8GC02815J ER -
@article{ author = "Petitjean, Laurene and de Winter, Tamara M. and Petrovic, Predrag V. and Coish, Philip and Hitce, Julien and Moreau, Magali and Bordier, Thierry and Erythropel, Hanno C. and Anastas, Paul T.", year = "2019", abstract = "We report a novel method for the reduction of α,β-unsaturated enones to the corresponding fully saturated alcohols in a single procedure. Remarkably, the method employs a heterogeneous copper catalyst in water and only requires resin-treatment for isolation of C-glycosidic alcohols as pure, diastereomeric mixtures. Our methodology was applied to the reduction of aromatic and aliphatic enones which furnished a library of C-glycosidic saturated alcohols from renewable sugars via a green and sustainable approach.", publisher = "Royal Society of Chemistry", journal = "Green Chemistry", title = "Heterogeneous copper-catalyzed direct reduction of C-glycosidic enones to saturated alcohols in water", volume = "21", pages = "238", doi = "10.1039/C8GC02815J" }
Petitjean, L., de Winter, T. M., Petrovic, P. V., Coish, P., Hitce, J., Moreau, M., Bordier, T., Erythropel, H. C.,& Anastas, P. T.. (2019). Heterogeneous copper-catalyzed direct reduction of C-glycosidic enones to saturated alcohols in water. in Green Chemistry Royal Society of Chemistry., 21, 238. https://doi.org/10.1039/C8GC02815J
Petitjean L, de Winter TM, Petrovic PV, Coish P, Hitce J, Moreau M, Bordier T, Erythropel HC, Anastas PT. Heterogeneous copper-catalyzed direct reduction of C-glycosidic enones to saturated alcohols in water. in Green Chemistry. 2019;21:238. doi:10.1039/C8GC02815J .
Petitjean, Laurene, de Winter, Tamara M., Petrovic, Predrag V., Coish, Philip, Hitce, Julien, Moreau, Magali, Bordier, Thierry, Erythropel, Hanno C., Anastas, Paul T., "Heterogeneous copper-catalyzed direct reduction of C-glycosidic enones to saturated alcohols in water" in Green Chemistry, 21 (2019):238, https://doi.org/10.1039/C8GC02815J . .