Platinum(IV) complex with pyridoxal semicarbazone
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The synthesis and characterization of a new ligand and the first complex with semicarbazide based ligand coordinated to platinum(IV) ion are reported. The new ligand, pyridoxal semicarbazone (H(2)PxSC), and complex [Pt(HPxSC)Cl-3] are characterized by elemental analysis, molar conductivity, infrared, electronic and H-1 NMR spectroscopy. The novel complex of platinum(IV) ion contains monoanionic, tridentate ONO ligand, and three chlorine ions. (C) 2003 Elsevier Science B.V. All rights reserved.
Keywords:platinum(IV) / pyridoxal semicarbazone / H-1 NMR spectroscopy / ONO system
Source:Inorganic Chemistry Communications, 2003, 6, 5, 561-564
- Elsevier Science Bv, Amsterdam