Ligand field analysis of metal-oxygen interactions-I. Tris(oxalato)cobaltate(III)
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Ligand field analysis of [Co(ox)3]3- has been performed using the angular overlap model (AOM) approach. The metal-oxygen interactions were treated as locally anisotropic. Experimental spectra were well reproduced by the calculations in which the Trees' correction was included. The effect of geometrical distortions on the calculated energies of ligand field states has been investigated. © 1991.