Ligand field analysis of metal-oxygen interactions-II. Tris(oxalato)chromate(III)
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Ligand field analysis of [Cr(ox)3]3- has been performed using the angular overlap model (AOM) approach. The metal-oxygen interactions were treated as locally anisotropic. The Trees' correction and the explicit treatment of the second coordination sphere were included. A set of parameters was derived which reproduces both the quartet bands and sharp doublet lines. Relationships between structural and spectral data were investigated. © 1991.