Crystal structure of (ethylenediammonium-N,N '-di-3-propanoic acid) tetrachloropalladate(II) complex
Само за регистроване кориснике
2004
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The title compound was obtained by a synthesis from ethylenediamine-N,N'-di-3-propanoic acid dihydrochloride (H(2)eddp . 2HCl) and potassium hexachloropalladate(IV) ( molar ratio 1: 1, in water). Its structure has been determined by single-crystal X-ray diffraction: monoclinic space group P2(1)/n, a = 8.198(1), b = 10.282(1), c = 9.080(1) Angstrom, beta = 103.62(1) degrees, V = 743.9(2) Angstrom(3), and Z = 2. The dianionic complex has a square-planar coordination geometry with four chloro ligands, and ethylenediamine-N,N'-di-3-propanoic acid as dication in the second coordination sphere. This is the first reported Pd(II) structure with uncoordinated H(2)eddp.
Кључне речи:
palladium(II) complex / eddp / crystal structure / square-planar geometryИзвор:
Journal of Chemical Crystallography, 2004, 34, 3, 185-189Издавач:
- Kluwer Academic/Plenum Publ, New York
DOI: 10.1023/B:JOCC.0000021562.41341.75
ISSN: 1074-1542
WoS: 000220451000004
Scopus: 2-s2.0-3843143813
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Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Kaluđerović, Goran N. AU - Heinemann, FW AU - Knezevic, NZ AU - Trifunović, Srećko R. AU - Sabo, Tibor PY - 2004 UR - https://cherry.chem.bg.ac.rs/handle/123456789/580 AB - The title compound was obtained by a synthesis from ethylenediamine-N,N'-di-3-propanoic acid dihydrochloride (H(2)eddp . 2HCl) and potassium hexachloropalladate(IV) ( molar ratio 1: 1, in water). Its structure has been determined by single-crystal X-ray diffraction: monoclinic space group P2(1)/n, a = 8.198(1), b = 10.282(1), c = 9.080(1) Angstrom, beta = 103.62(1) degrees, V = 743.9(2) Angstrom(3), and Z = 2. The dianionic complex has a square-planar coordination geometry with four chloro ligands, and ethylenediamine-N,N'-di-3-propanoic acid as dication in the second coordination sphere. This is the first reported Pd(II) structure with uncoordinated H(2)eddp. PB - Kluwer Academic/Plenum Publ, New York T2 - Journal of Chemical Crystallography T1 - Crystal structure of (ethylenediammonium-N,N '-di-3-propanoic acid) tetrachloropalladate(II) complex VL - 34 IS - 3 SP - 185 EP - 189 DO - 10.1023/B:JOCC.0000021562.41341.75 ER -
@article{ author = "Kaluđerović, Goran N. and Heinemann, FW and Knezevic, NZ and Trifunović, Srećko R. and Sabo, Tibor", year = "2004", abstract = "The title compound was obtained by a synthesis from ethylenediamine-N,N'-di-3-propanoic acid dihydrochloride (H(2)eddp . 2HCl) and potassium hexachloropalladate(IV) ( molar ratio 1: 1, in water). Its structure has been determined by single-crystal X-ray diffraction: monoclinic space group P2(1)/n, a = 8.198(1), b = 10.282(1), c = 9.080(1) Angstrom, beta = 103.62(1) degrees, V = 743.9(2) Angstrom(3), and Z = 2. The dianionic complex has a square-planar coordination geometry with four chloro ligands, and ethylenediamine-N,N'-di-3-propanoic acid as dication in the second coordination sphere. This is the first reported Pd(II) structure with uncoordinated H(2)eddp.", publisher = "Kluwer Academic/Plenum Publ, New York", journal = "Journal of Chemical Crystallography", title = "Crystal structure of (ethylenediammonium-N,N '-di-3-propanoic acid) tetrachloropalladate(II) complex", volume = "34", number = "3", pages = "185-189", doi = "10.1023/B:JOCC.0000021562.41341.75" }
Kaluđerović, G. N., Heinemann, F., Knezevic, N., Trifunović, S. R.,& Sabo, T.. (2004). Crystal structure of (ethylenediammonium-N,N '-di-3-propanoic acid) tetrachloropalladate(II) complex. in Journal of Chemical Crystallography Kluwer Academic/Plenum Publ, New York., 34(3), 185-189. https://doi.org/10.1023/B:JOCC.0000021562.41341.75
Kaluđerović GN, Heinemann F, Knezevic N, Trifunović SR, Sabo T. Crystal structure of (ethylenediammonium-N,N '-di-3-propanoic acid) tetrachloropalladate(II) complex. in Journal of Chemical Crystallography. 2004;34(3):185-189. doi:10.1023/B:JOCC.0000021562.41341.75 .
Kaluđerović, Goran N., Heinemann, FW, Knezevic, NZ, Trifunović, Srećko R., Sabo, Tibor, "Crystal structure of (ethylenediammonium-N,N '-di-3-propanoic acid) tetrachloropalladate(II) complex" in Journal of Chemical Crystallography, 34, no. 3 (2004):185-189, https://doi.org/10.1023/B:JOCC.0000021562.41341.75 . .