Synthesis, characterization and antimicrobial activity of cobalt(III) complex with (E)-4-(4-methoxyphenyl)-2-(2-(pyridin-2-ylmethylene)hydrazinyl)-1,3-selenazole
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
New cobalt complex with (E)-4-(4-methoxyphenyl)-2-(2-(pyridin-2-ylmethylene)hydrazinyl)-1,3-selenazole (HL) was synthesized and characterized in order to obtain biologically active compound. The complex was synthesized by the reaction of HL with cobalt(II) tetrafluoroborate. The complex was characterized by conductivity measurements, elemental analysis, FT-IR, 1H-NMR and 13C-NMR spectroscopy, while X-ray structural analysis (XRD) was used for molecular and crystal structure determination. XRD data elucidated that the complex has octahedral geometry with two ligands coordinated to cobalt(III) as tridentates, both in monoionic form, through pyridine, imine and selenazole nitrogen atoms (Fig. 1). In the outer sphere of the complex there is one tetrafluoroborate ion. The complex crystallizes as monohydrate. Antimicrobial activity of the ligand and complex was evaluated against eleven strains of bacteria and fungi. The complex showed better antibacterial than antifungal activity.
Извор:
Sixth Conference of Young Chemists of Serbia, Belgrade, 27th October 2018, 2018Издавач:
- Belgrade : Serbian Chemical Society
Финансирање / пројекти:
- Интеракције природних производа, њихових деривата и комплексних једињења са протеинима и нуклеинским киселинама (RS-MESTD-Basic Research (BR or ON)-172055)
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - CONF AU - Stojiljković, Uroš AU - Araškov, Jovana AU - Filipović, Nenad AU - Todorović, Tamara PY - 2018 UR - http://cherry.chem.bg.ac.rs/handle/123456789/5998 AB - New cobalt complex with (E)-4-(4-methoxyphenyl)-2-(2-(pyridin-2-ylmethylene)hydrazinyl)-1,3-selenazole (HL) was synthesized and characterized in order to obtain biologically active compound. The complex was synthesized by the reaction of HL with cobalt(II) tetrafluoroborate. The complex was characterized by conductivity measurements, elemental analysis, FT-IR, 1H-NMR and 13C-NMR spectroscopy, while X-ray structural analysis (XRD) was used for molecular and crystal structure determination. XRD data elucidated that the complex has octahedral geometry with two ligands coordinated to cobalt(III) as tridentates, both in monoionic form, through pyridine, imine and selenazole nitrogen atoms (Fig. 1). In the outer sphere of the complex there is one tetrafluoroborate ion. The complex crystallizes as monohydrate. Antimicrobial activity of the ligand and complex was evaluated against eleven strains of bacteria and fungi. The complex showed better antibacterial than antifungal activity. PB - Belgrade : Serbian Chemical Society C3 - Sixth Conference of Young Chemists of Serbia, Belgrade, 27th October 2018 T1 - Synthesis, characterization and antimicrobial activity of cobalt(III) complex with (E)-4-(4-methoxyphenyl)-2-(2-(pyridin-2-ylmethylene)hydrazinyl)-1,3-selenazole UR - https://hdl.handle.net/21.15107/rcub_cherry_5998 ER -
@conference{ author = "Stojiljković, Uroš and Araškov, Jovana and Filipović, Nenad and Todorović, Tamara", year = "2018", abstract = "New cobalt complex with (E)-4-(4-methoxyphenyl)-2-(2-(pyridin-2-ylmethylene)hydrazinyl)-1,3-selenazole (HL) was synthesized and characterized in order to obtain biologically active compound. The complex was synthesized by the reaction of HL with cobalt(II) tetrafluoroborate. The complex was characterized by conductivity measurements, elemental analysis, FT-IR, 1H-NMR and 13C-NMR spectroscopy, while X-ray structural analysis (XRD) was used for molecular and crystal structure determination. XRD data elucidated that the complex has octahedral geometry with two ligands coordinated to cobalt(III) as tridentates, both in monoionic form, through pyridine, imine and selenazole nitrogen atoms (Fig. 1). In the outer sphere of the complex there is one tetrafluoroborate ion. The complex crystallizes as monohydrate. Antimicrobial activity of the ligand and complex was evaluated against eleven strains of bacteria and fungi. The complex showed better antibacterial than antifungal activity.", publisher = "Belgrade : Serbian Chemical Society", journal = "Sixth Conference of Young Chemists of Serbia, Belgrade, 27th October 2018", title = "Synthesis, characterization and antimicrobial activity of cobalt(III) complex with (E)-4-(4-methoxyphenyl)-2-(2-(pyridin-2-ylmethylene)hydrazinyl)-1,3-selenazole", url = "https://hdl.handle.net/21.15107/rcub_cherry_5998" }
Stojiljković, U., Araškov, J., Filipović, N.,& Todorović, T.. (2018). Synthesis, characterization and antimicrobial activity of cobalt(III) complex with (E)-4-(4-methoxyphenyl)-2-(2-(pyridin-2-ylmethylene)hydrazinyl)-1,3-selenazole. in Sixth Conference of Young Chemists of Serbia, Belgrade, 27th October 2018 Belgrade : Serbian Chemical Society.. https://hdl.handle.net/21.15107/rcub_cherry_5998
Stojiljković U, Araškov J, Filipović N, Todorović T. Synthesis, characterization and antimicrobial activity of cobalt(III) complex with (E)-4-(4-methoxyphenyl)-2-(2-(pyridin-2-ylmethylene)hydrazinyl)-1,3-selenazole. in Sixth Conference of Young Chemists of Serbia, Belgrade, 27th October 2018. 2018;. https://hdl.handle.net/21.15107/rcub_cherry_5998 .
Stojiljković, Uroš, Araškov, Jovana, Filipović, Nenad, Todorović, Tamara, "Synthesis, characterization and antimicrobial activity of cobalt(III) complex with (E)-4-(4-methoxyphenyl)-2-(2-(pyridin-2-ylmethylene)hydrazinyl)-1,3-selenazole" in Sixth Conference of Young Chemists of Serbia, Belgrade, 27th October 2018 (2018), https://hdl.handle.net/21.15107/rcub_cherry_5998 .