Cyclization/alkoxy radical fragmentation tandem: An efficient approach to the synthesis of bridged cyclooctane derivatives

dc.creator	Saičić, Radomir
dc.creator	Čeković, Živorad
dc.date.accessioned	2018-11-22T00:01:30Z
dc.date.available	2018-11-22T00:01:30Z
dc.date.issued	1997
dc.identifier.issn	0352-5139
dc.identifier.uri	https://cherry.chem.bg.ac.rs/handle/123456789/59
dc.description.abstract	In this paper an efficient synthetic approach to bridged cyclooctanone framework is described, which is based on cyclization/alkoxy radical fragmentation as a tactical combination of reactions. While the hypoiodite reaction of alcohol 11 proceeds in a normal fashion, the hypobromite reaction of the same precursor unexpectedly affords dibromo derivative 14, which, in turn, shows unusual reactivity in the presence of cesium acetate.	en
dc.rights	restrictedAccess
dc.rights.uri	https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source	Journal of the Serbian Chemical Society
dc.subject	Aldol reaction	en
dc.subject	Cyclooctane	en
dc.subject	Fragmentation	en
dc.subject	Radicals	en
dc.subject	Taxane	en
dc.title	Cyclization/alkoxy radical fragmentation tandem: An efficient approach to the synthesis of bridged cyclooctane derivatives	en
dc.type	article
dc.rights.license	BY-NC-ND
dc.citation.volume	62
dc.citation.issue	9
dc.citation.spage	727
dc.citation.epage	735
dc.citation.other	62(9): 727-735
dc.type.version	publishedVersion	en
dc.identifier.scopus	2-s2.0-0040090211
dc.identifier.rcub	https://hdl.handle.net/21.15107/rcub_cherry_59

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