Tetraaquabis(D-camphor-10-sulfonato)calcium(II)
Нема приказа
Аутори
Jeremić, DejanKaluđerović, Goran N.
Gomez-Ruiz, Santiago
Brčeski, Ilija
Anđelković, Katarina K.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The structure of the title compound, [Ca(C(10)H(15)O(4)S)(2)(H(2)O)(4)], is the first example in which two d-camphor-10-sulfonate anions are coordinated to a metal ion, in this case with direct Ca-O bonding. The molecule has crystallographically imposed twofold symmetry with the Ca atom on the twofold axis. Hydrogen bonds are formed between the coordinated water molecules and the O atoms of the SO(3)(-) groups of adjacent molecules, leading to the formation of a two-dimensional layered network. The compound displays sharp wavelength-selective transparency in the UV-visible spectrum, offering the potential for application as an optical filter.
Извор:
Acta Crystallographica. Section C: Crystal Structure Communications, 2009, 65Издавач:
- Wiley-Blackwell Publishing, Inc, Malden
Финансирање / пројекти:
- Синтеза, анализа и активност нових органских полидентатних лиганада и њихових комплекса са d-металима (RS-MESTD-MPN2006-2010-142062)
DOI: 10.1107/S0108270109004193
ISSN: 0108-2701
PubMed: 19346597
WoS: 000264769800006
Scopus: 2-s2.0-64249093470
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Jeremić, Dejan AU - Kaluđerović, Goran N. AU - Gomez-Ruiz, Santiago AU - Brčeski, Ilija AU - Anđelković, Katarina K. PY - 2009 UR - https://cherry.chem.bg.ac.rs/handle/123456789/620 AB - The structure of the title compound, [Ca(C(10)H(15)O(4)S)(2)(H(2)O)(4)], is the first example in which two d-camphor-10-sulfonate anions are coordinated to a metal ion, in this case with direct Ca-O bonding. The molecule has crystallographically imposed twofold symmetry with the Ca atom on the twofold axis. Hydrogen bonds are formed between the coordinated water molecules and the O atoms of the SO(3)(-) groups of adjacent molecules, leading to the formation of a two-dimensional layered network. The compound displays sharp wavelength-selective transparency in the UV-visible spectrum, offering the potential for application as an optical filter. PB - Wiley-Blackwell Publishing, Inc, Malden T2 - Acta Crystallographica. Section C: Crystal Structure Communications T1 - Tetraaquabis(D-camphor-10-sulfonato)calcium(II) VL - 65 DO - 10.1107/S0108270109004193 ER -
@article{ author = "Jeremić, Dejan and Kaluđerović, Goran N. and Gomez-Ruiz, Santiago and Brčeski, Ilija and Anđelković, Katarina K.", year = "2009", abstract = "The structure of the title compound, [Ca(C(10)H(15)O(4)S)(2)(H(2)O)(4)], is the first example in which two d-camphor-10-sulfonate anions are coordinated to a metal ion, in this case with direct Ca-O bonding. The molecule has crystallographically imposed twofold symmetry with the Ca atom on the twofold axis. Hydrogen bonds are formed between the coordinated water molecules and the O atoms of the SO(3)(-) groups of adjacent molecules, leading to the formation of a two-dimensional layered network. The compound displays sharp wavelength-selective transparency in the UV-visible spectrum, offering the potential for application as an optical filter.", publisher = "Wiley-Blackwell Publishing, Inc, Malden", journal = "Acta Crystallographica. Section C: Crystal Structure Communications", title = "Tetraaquabis(D-camphor-10-sulfonato)calcium(II)", volume = "65", doi = "10.1107/S0108270109004193" }
Jeremić, D., Kaluđerović, G. N., Gomez-Ruiz, S., Brčeski, I.,& Anđelković, K. K.. (2009). Tetraaquabis(D-camphor-10-sulfonato)calcium(II). in Acta Crystallographica. Section C: Crystal Structure Communications Wiley-Blackwell Publishing, Inc, Malden., 65. https://doi.org/10.1107/S0108270109004193
Jeremić D, Kaluđerović GN, Gomez-Ruiz S, Brčeski I, Anđelković KK. Tetraaquabis(D-camphor-10-sulfonato)calcium(II). in Acta Crystallographica. Section C: Crystal Structure Communications. 2009;65. doi:10.1107/S0108270109004193 .
Jeremić, Dejan, Kaluđerović, Goran N., Gomez-Ruiz, Santiago, Brčeski, Ilija, Anđelković, Katarina K., "Tetraaquabis(D-camphor-10-sulfonato)calcium(II)" in Acta Crystallographica. Section C: Crystal Structure Communications, 65 (2009), https://doi.org/10.1107/S0108270109004193 . .