Mechanochemical synthesis and characterization of the adsorbents based on natural zeolite and hydroxyapatite
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Natural zeolite is a good sorbent for many cations due to its specific porous structure. The degree of sorption efficiency depends on the cation type and the availability of exchange positions in the zeolite lattice. The aim of this work is to
examine the synthesis possibility of a new adsorbent based on natural zeolite and hydroxyapatite. The adsorbent was prepared mechanochemically by using clinoptilolite-rich zeolite tuff from the Slanci deposit (Serbia) and hydroxyapatite
obtained by the hydrothermal process. The milling process was performed in a ball mill and optimized regarding contact time and milling speed. For the synthesis of zeolite/hydroxyapatite adsorbent (ZHAp), optimal values for these two parameters were 10 min and 250 rpm, respectively. The resulting sample ZHAp was characterized by X-ray powder diffraction, thermal analysis and scanning electron microscopy. Diffraction analysis of the ZHAp confirmed the presence of the most abundant mineral in zeolite tuff - clinop...tilolite and hydroxyapatite. Needle-like crystals of hydroxyapatite on the clinoptilolite surface are observed in SEM images. Zeolite/hydroxyapatite sample is thermally stable at 800 °C. Adsorption properties of ZHAp were examined for nickel and chromium ions, towards which natural zeolite shows a low affinity. The presence of hydroxyapatite on the zeolite surface led to an increase in the adsorption capacity more than two times for both tested ions compared to the initial zeolite tuff.
Кључне речи:
mechanochemical synthesis / natural zeolite / hydroxyapatite / adsorptionИзвор:
5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE Congress 2023, Trebinje, Bosnia and Herzegovina 7-10th June 2023, 2023, 395-400Издавач:
- Association of Metallurgical Engineers of Serbia (AMES)
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200135 (Универзитет у Београду, Технолошко-металуршки факултет) (RS-MESTD-inst-2020-200135)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200287 (Иновациони центар Технолошко-металуршког факултета у Београду доо) (RS-MESTD-inst-2020-200287)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200288 (Иновациони центар Хемијског факултета у Београду доо) (RS-MESTD-inst-2020-200288)
Колекције
Институција/група
Inovacioni centar / Innovation CentreTY - CONF AU - Sokić, Katarina AU - Dikić, Jelena AU - Veljović, Đorđe AU - Đokić, Jovana AU - Anđić, Zoran AU - Jevtić, Sanja O. PY - 2023 UR - http://cherry.chem.bg.ac.rs/handle/123456789/6243 AB - Natural zeolite is a good sorbent for many cations due to its specific porous structure. The degree of sorption efficiency depends on the cation type and the availability of exchange positions in the zeolite lattice. The aim of this work is to examine the synthesis possibility of a new adsorbent based on natural zeolite and hydroxyapatite. The adsorbent was prepared mechanochemically by using clinoptilolite-rich zeolite tuff from the Slanci deposit (Serbia) and hydroxyapatite obtained by the hydrothermal process. The milling process was performed in a ball mill and optimized regarding contact time and milling speed. For the synthesis of zeolite/hydroxyapatite adsorbent (ZHAp), optimal values for these two parameters were 10 min and 250 rpm, respectively. The resulting sample ZHAp was characterized by X-ray powder diffraction, thermal analysis and scanning electron microscopy. Diffraction analysis of the ZHAp confirmed the presence of the most abundant mineral in zeolite tuff - clinoptilolite and hydroxyapatite. Needle-like crystals of hydroxyapatite on the clinoptilolite surface are observed in SEM images. Zeolite/hydroxyapatite sample is thermally stable at 800 °C. Adsorption properties of ZHAp were examined for nickel and chromium ions, towards which natural zeolite shows a low affinity. The presence of hydroxyapatite on the zeolite surface led to an increase in the adsorption capacity more than two times for both tested ions compared to the initial zeolite tuff. PB - Association of Metallurgical Engineers of Serbia (AMES) C3 - 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE Congress 2023, Trebinje, Bosnia and Herzegovina 7-10th June 2023 T1 - Mechanochemical synthesis and characterization of the adsorbents based on natural zeolite and hydroxyapatite SP - 395 EP - 400 UR - https://hdl.handle.net/21.15107/rcub_cherry_6243 ER -
@conference{ author = "Sokić, Katarina and Dikić, Jelena and Veljović, Đorđe and Đokić, Jovana and Anđić, Zoran and Jevtić, Sanja O.", year = "2023", abstract = "Natural zeolite is a good sorbent for many cations due to its specific porous structure. The degree of sorption efficiency depends on the cation type and the availability of exchange positions in the zeolite lattice. The aim of this work is to examine the synthesis possibility of a new adsorbent based on natural zeolite and hydroxyapatite. The adsorbent was prepared mechanochemically by using clinoptilolite-rich zeolite tuff from the Slanci deposit (Serbia) and hydroxyapatite obtained by the hydrothermal process. The milling process was performed in a ball mill and optimized regarding contact time and milling speed. For the synthesis of zeolite/hydroxyapatite adsorbent (ZHAp), optimal values for these two parameters were 10 min and 250 rpm, respectively. The resulting sample ZHAp was characterized by X-ray powder diffraction, thermal analysis and scanning electron microscopy. Diffraction analysis of the ZHAp confirmed the presence of the most abundant mineral in zeolite tuff - clinoptilolite and hydroxyapatite. Needle-like crystals of hydroxyapatite on the clinoptilolite surface are observed in SEM images. Zeolite/hydroxyapatite sample is thermally stable at 800 °C. Adsorption properties of ZHAp were examined for nickel and chromium ions, towards which natural zeolite shows a low affinity. The presence of hydroxyapatite on the zeolite surface led to an increase in the adsorption capacity more than two times for both tested ions compared to the initial zeolite tuff.", publisher = "Association of Metallurgical Engineers of Serbia (AMES)", journal = "5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE Congress 2023, Trebinje, Bosnia and Herzegovina 7-10th June 2023", title = "Mechanochemical synthesis and characterization of the adsorbents based on natural zeolite and hydroxyapatite", pages = "395-400", url = "https://hdl.handle.net/21.15107/rcub_cherry_6243" }
Sokić, K., Dikić, J., Veljović, Đ., Đokić, J., Anđić, Z.,& Jevtić, S. O.. (2023). Mechanochemical synthesis and characterization of the adsorbents based on natural zeolite and hydroxyapatite. in 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE Congress 2023, Trebinje, Bosnia and Herzegovina 7-10th June 2023 Association of Metallurgical Engineers of Serbia (AMES)., 395-400. https://hdl.handle.net/21.15107/rcub_cherry_6243
Sokić K, Dikić J, Veljović Đ, Đokić J, Anđić Z, Jevtić SO. Mechanochemical synthesis and characterization of the adsorbents based on natural zeolite and hydroxyapatite. in 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE Congress 2023, Trebinje, Bosnia and Herzegovina 7-10th June 2023. 2023;:395-400. https://hdl.handle.net/21.15107/rcub_cherry_6243 .
Sokić, Katarina, Dikić, Jelena, Veljović, Đorđe, Đokić, Jovana, Anđić, Zoran, Jevtić, Sanja O., "Mechanochemical synthesis and characterization of the adsorbents based on natural zeolite and hydroxyapatite" in 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE Congress 2023, Trebinje, Bosnia and Herzegovina 7-10th June 2023 (2023):395-400, https://hdl.handle.net/21.15107/rcub_cherry_6243 .