Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey
Само за регистроване кориснике
2023
Аутори
Jevtović, MimaPevec, Andrej
Turel, Iztok
Radanović, Dušanka
Milčić, Miloš K.
Gruden, Maja
Zlatar, Matija
Mitić, Dragana
Anđelković, Katarina K.
Čobeljić, Božidar
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
In this paper, we report the synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex, [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex, [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient conditions.
Кључне речи:
Schiff base ligands / nickel(II) / nickel(III) / complexes / synthesis / X-ray structure / DFT / syngle crystal / EPRИзвор:
Inorganic Chemistry Communications, 2023, 158, 111582-Издавач:
- Elsevier
Финансирање / пројекти:
- TMMagCat - Tailoring Molecular Magnets and Catalysts Based on Transition Metal Complexes (RS-ScienceFundRS-Ideje-7750288)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200026 (Универзитет у Београду, Институт за хемију, технологију и металургију - ИХТМ) (RS-MESTD-inst-2020-200026)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200168 (Универзитет у Београду, Хемијски факултет) (RS-MESTD-inst-2020-200168)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200288 (Иновациони центар Хемијског факултета у Београду доо) (RS-MESTD-inst-2020-200288)
- Slovenian Research Agency (ARRS), grant number P1-0175
Повезане информације:
- Верзија документа
https://cer.ihtm.bg.ac.rs/handle/123456789/6766
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Jevtović, Mima AU - Pevec, Andrej AU - Turel, Iztok AU - Radanović, Dušanka AU - Milčić, Miloš K. AU - Gruden, Maja AU - Zlatar, Matija AU - Mitić, Dragana AU - Anđelković, Katarina K. AU - Čobeljić, Božidar PY - 2023 UR - http://cherry.chem.bg.ac.rs/handle/123456789/6381 AB - In this paper, we report the synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex, [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex, [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient conditions. PB - Elsevier T2 - Inorganic Chemistry Communications T1 - Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey VL - 158 SP - 111582 DO - 10.1016/j.inoche.2023.111582 ER -
@article{ author = "Jevtović, Mima and Pevec, Andrej and Turel, Iztok and Radanović, Dušanka and Milčić, Miloš K. and Gruden, Maja and Zlatar, Matija and Mitić, Dragana and Anđelković, Katarina K. and Čobeljić, Božidar", year = "2023", abstract = "In this paper, we report the synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex, [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex, [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient conditions.", publisher = "Elsevier", journal = "Inorganic Chemistry Communications", title = "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey", volume = "158", pages = "111582", doi = "10.1016/j.inoche.2023.111582" }
Jevtović, M., Pevec, A., Turel, I., Radanović, D., Milčić, M. K., Gruden, M., Zlatar, M., Mitić, D., Anđelković, K. K.,& Čobeljić, B.. (2023). Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey. in Inorganic Chemistry Communications Elsevier., 158, 111582. https://doi.org/10.1016/j.inoche.2023.111582
Jevtović M, Pevec A, Turel I, Radanović D, Milčić MK, Gruden M, Zlatar M, Mitić D, Anđelković KK, Čobeljić B. Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey. in Inorganic Chemistry Communications. 2023;158:111582. doi:10.1016/j.inoche.2023.111582 .
Jevtović, Mima, Pevec, Andrej, Turel, Iztok, Radanović, Dušanka, Milčić, Miloš K., Gruden, Maja, Zlatar, Matija, Mitić, Dragana, Anđelković, Katarina K., Čobeljić, Božidar, "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey" in Inorganic Chemistry Communications, 158 (2023):111582, https://doi.org/10.1016/j.inoche.2023.111582 . .