Intramolecular C-H center dot center dot center dot pi interactions in metal-porphyrin complexes
Апстракт
Cambridge Structural Database (CSD) was screened in order to find intramolecular C-H...pi interactions with a chelate ring of coordinated porphyrin. It was found 154 crystal structures with 244 intramolecular C-H...pi interactions in transition metal complexes with derivatives of porphyrin. Comparison of interacting distances indicates that interactions of hydrogen atoms in positions 2 and 6 of axially coordinated pyridine are more favorable with ruffled than with planar porphyrin.
Кључне речи:
C-H center dot center dot center dot pi interactions / transition metal complexes / chelate ring / porphyrin / axial ligandsИзвор:
International Journal of Molecular Sciences, 2004, 5, 4-7, 174-185Издавач:
- Mdpi Ag, Basel
DOI: 10.3390/i5040174
ISSN: 1422-0067
WoS: 000221895100005
Scopus: 2-s2.0-19744364416
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Bogdanović, Goran A. AU - Medaković, Vesna AU - Milčić, Miloš K. AU - Zarić, Snežana D. PY - 2004 UR - https://cherry.chem.bg.ac.rs/handle/123456789/644 AB - Cambridge Structural Database (CSD) was screened in order to find intramolecular C-H...pi interactions with a chelate ring of coordinated porphyrin. It was found 154 crystal structures with 244 intramolecular C-H...pi interactions in transition metal complexes with derivatives of porphyrin. Comparison of interacting distances indicates that interactions of hydrogen atoms in positions 2 and 6 of axially coordinated pyridine are more favorable with ruffled than with planar porphyrin. PB - Mdpi Ag, Basel T2 - International Journal of Molecular Sciences T1 - Intramolecular C-H center dot center dot center dot pi interactions in metal-porphyrin complexes VL - 5 IS - 4-7 SP - 174 EP - 185 DO - 10.3390/i5040174 ER -
@article{ author = "Bogdanović, Goran A. and Medaković, Vesna and Milčić, Miloš K. and Zarić, Snežana D.", year = "2004", abstract = "Cambridge Structural Database (CSD) was screened in order to find intramolecular C-H...pi interactions with a chelate ring of coordinated porphyrin. It was found 154 crystal structures with 244 intramolecular C-H...pi interactions in transition metal complexes with derivatives of porphyrin. Comparison of interacting distances indicates that interactions of hydrogen atoms in positions 2 and 6 of axially coordinated pyridine are more favorable with ruffled than with planar porphyrin.", publisher = "Mdpi Ag, Basel", journal = "International Journal of Molecular Sciences", title = "Intramolecular C-H center dot center dot center dot pi interactions in metal-porphyrin complexes", volume = "5", number = "4-7", pages = "174-185", doi = "10.3390/i5040174" }
Bogdanović, G. A., Medaković, V., Milčić, M. K.,& Zarić, S. D.. (2004). Intramolecular C-H center dot center dot center dot pi interactions in metal-porphyrin complexes. in International Journal of Molecular Sciences Mdpi Ag, Basel., 5(4-7), 174-185. https://doi.org/10.3390/i5040174
Bogdanović GA, Medaković V, Milčić MK, Zarić SD. Intramolecular C-H center dot center dot center dot pi interactions in metal-porphyrin complexes. in International Journal of Molecular Sciences. 2004;5(4-7):174-185. doi:10.3390/i5040174 .
Bogdanović, Goran A., Medaković, Vesna, Milčić, Miloš K., Zarić, Snežana D., "Intramolecular C-H center dot center dot center dot pi interactions in metal-porphyrin complexes" in International Journal of Molecular Sciences, 5, no. 4-7 (2004):174-185, https://doi.org/10.3390/i5040174 . .
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