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Intramolecular C-H center dot center dot center dot pi interactions in metal-porphyrin complexes

dc.creatorBogdanović, Goran A.
dc.creatorMedaković, Vesna
dc.creatorMilčić, Miloš K.
dc.creatorZarić, Snežana D.
dc.date.accessioned2018-11-22T00:07:05Z
dc.date.available2018-11-22T00:07:05Z
dc.date.issued2004
dc.identifier.issn1422-0067
dc.identifier.urihttps://cherry.chem.bg.ac.rs/handle/123456789/644
dc.description.abstractCambridge Structural Database (CSD) was screened in order to find intramolecular C-H...pi interactions with a chelate ring of coordinated porphyrin. It was found 154 crystal structures with 244 intramolecular C-H...pi interactions in transition metal complexes with derivatives of porphyrin. Comparison of interacting distances indicates that interactions of hydrogen atoms in positions 2 and 6 of axially coordinated pyridine are more favorable with ruffled than with planar porphyrin.en
dc.publisherMdpi Ag, Basel
dc.rightsopenAccess
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.sourceInternational Journal of Molecular Sciences
dc.subjectC-H center dot center dot center dot pi interactionsen
dc.subjecttransition metal complexesen
dc.subjectchelate ringen
dc.subjectporphyrinen
dc.subjectaxial ligandsen
dc.titleIntramolecular C-H center dot center dot center dot pi interactions in metal-porphyrin complexesen
dc.typearticle
dc.rights.licenseBY
dcterms.abstractЗарић, Снежана; Богдановиц, ГA; Медаковић, Весна; Милчић, Милош;
dc.citation.volume5
dc.citation.issue4-7
dc.citation.spage174
dc.citation.epage185
dc.identifier.wos000221895100005
dc.identifier.doi10.3390/i5040174
dc.citation.other5(4-7): 174-185
dc.type.versionpublishedVersion
dc.identifier.scopus2-s2.0-19744364416
dc.identifier.fulltexthttps://cherry.chem.bg.ac.rs/bitstream/id/9890/642.pdf


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