Inorganic analysis of herbal drugs. Part I. Metal determination in herbal drugs originating from medicinal plants of the family Lamiacae
Neorganska analiza biljnih droga, I deo - određivanje metala u biljnim drogama dobijenih iz biljaka familije Lamiacae
Апстракт
Elemental profiles of the total analyte content of major, minor and trace elements (Cu, Zn, Mn, Fe, K, Ca, Mg, Al, Ba and 13) in 8 herbal drugs, originating from medicinal plants of the family Lamiacae, were determined. Flame atomic absorption/emission spectroscopy (FAAS/FAES), inductively coupled plasma atomic emission spectroscopy (ICP-AES) and energy dispersive X-ray fluorescence (EDXRF) were applied, and the advantages and limitations of these techniques are also discussed. The whole procedure, from sample preparation via dissolution to the actual measurements, was validated byusing CRM (NIST 1573a-Tomato leaves). The recovery values obtained were in the range 90.64 - 101.58%. A high degree of similarity in their elemental profiles was noticed from the results of qualitative analysis, while quantitative analysis shows significant diversity due to the variety of the influencing sources. The medicinal plants investigated in this work contained Cu (5.92 - 14.79 mg kg(-1)), Zn (15.0 - ...43.0 mg kg(-1)), Mn (25 - 111 mg kg(-1)), Fe (74 - 546 mg kg(-1)), K (1.80 - 6.24 %), Ca (0.90 - 1.43 %), Mg (0. 17 - 0.67 %), Al (49 - 378 mg kg(-1)), Ba (15.53 - 69.84 mg kg(-1)) and B (34.7 - 56.5 mg kg(-1)).
Određeni su profili elemenata, izraženi kao ukupan sadržaj glavnih komponenti i tragova (Cu, Zn,Mn, Fe,K,Ca, Mg,Al, Ba i B) u 8 biljnih droga, dobijenih iz biljaka familije Lamiacae. U analizi su primenjene metode: plamena atomska apsorpciona/ emisiona spektroskopija, atomska emisiona spektroskopija sa induktivno spregnutom plazmom i fluorescentna rendgenska analiza sa disperzijom energije. Diskutovane su prednosti i ograničenja primenjenih metoda analize. Metodološki postupak od pripreme uzoraka, do merenja proveren je i potvrđen primenom sertifikovanog standardnog materijala (NIST 1573a - Tomato leaves). Statističkom obradom rezultata dobijeni su procenti prinosa u opsegu 90.64 - 101.58 %. Rezultati kvalitativne analize ukazuju na veliki stepen sličnosti u sastavu neorganskih analita. Kvantitativnom analizom određen je sadržaj 10 elemenata i uočena različitost koncentracionih profila. Analizirane biljne droge sadrže: Cu (5.92 - 14.79 mg kg-1), Zn (15.0 - 43.0mg kg-1), Mn (25 - 111 mg... kg-1), Fe (74 - 546 mg kg-1), K (1.80 - 6.24 %), Ca (0.90 - 1.43 %), Mg (0.17 - 0.67 %), Al (49 - 378 mg kg-1), Ba (15.53 - 69.84 mg kg-1) and B (34.7 - 56.5mg kg -1).
Кључне речи:
major / minor and trace elements / minor and trace elements / FAAS / FAAS / FAES / FAES / ICP-AES / ICP-AES / EDXRF / EDXRF / herbal drugs / herbal drugs / Lamiacae / LamiacaeИзвор:
Journal of the Serbian Chemical Society, 2005, 70, 11, 1347-1355Издавач:
- Serbian Chemical Soc, Belgrade
DOI: 10.2298/JSC0511347R
ISSN: 0352-5139
WoS: 000234277000012
Scopus: 2-s2.0-31544475454
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Razic, S AU - Dogo, S AU - Slavković, Latinka AU - Popović, Aleksandar R. PY - 2005 UR - https://cherry.chem.bg.ac.rs/handle/123456789/746 AB - Elemental profiles of the total analyte content of major, minor and trace elements (Cu, Zn, Mn, Fe, K, Ca, Mg, Al, Ba and 13) in 8 herbal drugs, originating from medicinal plants of the family Lamiacae, were determined. Flame atomic absorption/emission spectroscopy (FAAS/FAES), inductively coupled plasma atomic emission spectroscopy (ICP-AES) and energy dispersive X-ray fluorescence (EDXRF) were applied, and the advantages and limitations of these techniques are also discussed. The whole procedure, from sample preparation via dissolution to the actual measurements, was validated byusing CRM (NIST 1573a-Tomato leaves). The recovery values obtained were in the range 90.64 - 101.58%. A high degree of similarity in their elemental profiles was noticed from the results of qualitative analysis, while quantitative analysis shows significant diversity due to the variety of the influencing sources. The medicinal plants investigated in this work contained Cu (5.92 - 14.79 mg kg(-1)), Zn (15.0 - 43.0 mg kg(-1)), Mn (25 - 111 mg kg(-1)), Fe (74 - 546 mg kg(-1)), K (1.80 - 6.24 %), Ca (0.90 - 1.43 %), Mg (0. 17 - 0.67 %), Al (49 - 378 mg kg(-1)), Ba (15.53 - 69.84 mg kg(-1)) and B (34.7 - 56.5 mg kg(-1)). AB - Određeni su profili elemenata, izraženi kao ukupan sadržaj glavnih komponenti i tragova (Cu, Zn,Mn, Fe,K,Ca, Mg,Al, Ba i B) u 8 biljnih droga, dobijenih iz biljaka familije Lamiacae. U analizi su primenjene metode: plamena atomska apsorpciona/ emisiona spektroskopija, atomska emisiona spektroskopija sa induktivno spregnutom plazmom i fluorescentna rendgenska analiza sa disperzijom energije. Diskutovane su prednosti i ograničenja primenjenih metoda analize. Metodološki postupak od pripreme uzoraka, do merenja proveren je i potvrđen primenom sertifikovanog standardnog materijala (NIST 1573a - Tomato leaves). Statističkom obradom rezultata dobijeni su procenti prinosa u opsegu 90.64 - 101.58 %. Rezultati kvalitativne analize ukazuju na veliki stepen sličnosti u sastavu neorganskih analita. Kvantitativnom analizom određen je sadržaj 10 elemenata i uočena različitost koncentracionih profila. Analizirane biljne droge sadrže: Cu (5.92 - 14.79 mg kg-1), Zn (15.0 - 43.0mg kg-1), Mn (25 - 111 mg kg-1), Fe (74 - 546 mg kg-1), K (1.80 - 6.24 %), Ca (0.90 - 1.43 %), Mg (0.17 - 0.67 %), Al (49 - 378 mg kg-1), Ba (15.53 - 69.84 mg kg-1) and B (34.7 - 56.5mg kg -1). PB - Serbian Chemical Soc, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Inorganic analysis of herbal drugs. Part I. Metal determination in herbal drugs originating from medicinal plants of the family Lamiacae T1 - Neorganska analiza biljnih droga, I deo - određivanje metala u biljnim drogama dobijenih iz biljaka familije Lamiacae VL - 70 IS - 11 SP - 1347 EP - 1355 DO - 10.2298/JSC0511347R ER -
@article{ author = "Razic, S and Dogo, S and Slavković, Latinka and Popović, Aleksandar R.", year = "2005", abstract = "Elemental profiles of the total analyte content of major, minor and trace elements (Cu, Zn, Mn, Fe, K, Ca, Mg, Al, Ba and 13) in 8 herbal drugs, originating from medicinal plants of the family Lamiacae, were determined. Flame atomic absorption/emission spectroscopy (FAAS/FAES), inductively coupled plasma atomic emission spectroscopy (ICP-AES) and energy dispersive X-ray fluorescence (EDXRF) were applied, and the advantages and limitations of these techniques are also discussed. The whole procedure, from sample preparation via dissolution to the actual measurements, was validated byusing CRM (NIST 1573a-Tomato leaves). The recovery values obtained were in the range 90.64 - 101.58%. A high degree of similarity in their elemental profiles was noticed from the results of qualitative analysis, while quantitative analysis shows significant diversity due to the variety of the influencing sources. The medicinal plants investigated in this work contained Cu (5.92 - 14.79 mg kg(-1)), Zn (15.0 - 43.0 mg kg(-1)), Mn (25 - 111 mg kg(-1)), Fe (74 - 546 mg kg(-1)), K (1.80 - 6.24 %), Ca (0.90 - 1.43 %), Mg (0. 17 - 0.67 %), Al (49 - 378 mg kg(-1)), Ba (15.53 - 69.84 mg kg(-1)) and B (34.7 - 56.5 mg kg(-1))., Određeni su profili elemenata, izraženi kao ukupan sadržaj glavnih komponenti i tragova (Cu, Zn,Mn, Fe,K,Ca, Mg,Al, Ba i B) u 8 biljnih droga, dobijenih iz biljaka familije Lamiacae. U analizi su primenjene metode: plamena atomska apsorpciona/ emisiona spektroskopija, atomska emisiona spektroskopija sa induktivno spregnutom plazmom i fluorescentna rendgenska analiza sa disperzijom energije. Diskutovane su prednosti i ograničenja primenjenih metoda analize. Metodološki postupak od pripreme uzoraka, do merenja proveren je i potvrđen primenom sertifikovanog standardnog materijala (NIST 1573a - Tomato leaves). Statističkom obradom rezultata dobijeni su procenti prinosa u opsegu 90.64 - 101.58 %. Rezultati kvalitativne analize ukazuju na veliki stepen sličnosti u sastavu neorganskih analita. Kvantitativnom analizom određen je sadržaj 10 elemenata i uočena različitost koncentracionih profila. Analizirane biljne droge sadrže: Cu (5.92 - 14.79 mg kg-1), Zn (15.0 - 43.0mg kg-1), Mn (25 - 111 mg kg-1), Fe (74 - 546 mg kg-1), K (1.80 - 6.24 %), Ca (0.90 - 1.43 %), Mg (0.17 - 0.67 %), Al (49 - 378 mg kg-1), Ba (15.53 - 69.84 mg kg-1) and B (34.7 - 56.5mg kg -1).", publisher = "Serbian Chemical Soc, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Inorganic analysis of herbal drugs. Part I. Metal determination in herbal drugs originating from medicinal plants of the family Lamiacae, Neorganska analiza biljnih droga, I deo - određivanje metala u biljnim drogama dobijenih iz biljaka familije Lamiacae", volume = "70", number = "11", pages = "1347-1355", doi = "10.2298/JSC0511347R" }
Razic, S., Dogo, S., Slavković, L.,& Popović, A. R.. (2005). Inorganic analysis of herbal drugs. Part I. Metal determination in herbal drugs originating from medicinal plants of the family Lamiacae. in Journal of the Serbian Chemical Society Serbian Chemical Soc, Belgrade., 70(11), 1347-1355. https://doi.org/10.2298/JSC0511347R
Razic S, Dogo S, Slavković L, Popović AR. Inorganic analysis of herbal drugs. Part I. Metal determination in herbal drugs originating from medicinal plants of the family Lamiacae. in Journal of the Serbian Chemical Society. 2005;70(11):1347-1355. doi:10.2298/JSC0511347R .
Razic, S, Dogo, S, Slavković, Latinka, Popović, Aleksandar R., "Inorganic analysis of herbal drugs. Part I. Metal determination in herbal drugs originating from medicinal plants of the family Lamiacae" in Journal of the Serbian Chemical Society, 70, no. 11 (2005):1347-1355, https://doi.org/10.2298/JSC0511347R . .