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Allosteric regulation of the conformational dynamics of a cavitand receptor
dc.creator | Yan, Zhiqing | |
dc.creator | Chang, Yuning | |
dc.creator | Mayo, Dennis | |
dc.creator | Maslak, Veselin | |
dc.creator | Xia, Shijing | |
dc.creator | Bađić, Jovica D. | |
dc.date.accessioned | 2018-11-22T00:09:57Z | |
dc.date.available | 2018-11-22T00:09:57Z | |
dc.date.issued | 2006 | |
dc.identifier.issn | 1523-7060 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/795 | |
dc.description.abstract | Inspired by allostery in nature, we synthesized cavitand 1 and investigated regulation of its conformational dynamics. Quantitative H-1 NMR studies have revealed that the rate of the conformational isomerization of 1 can be modulated using the external addition of acid. As 1 maintains its vase-like conformation in an acidic environment, ample opportunities for controlling the kinetics of molecular recognition, and thus reactivity, in this and related receptors have arisen. | en |
dc.publisher | Amer Chemical Soc, Washington | |
dc.rights | restrictedAccess | |
dc.source | Organic Letters | |
dc.title | Allosteric regulation of the conformational dynamics of a cavitand receptor | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Бадјиц, Јовица Д.; Цханг, Yунинг; Yан, Зхиqинг; Маyо, Деннис; Маслак, Веселин; Xиа, Схијинг; | |
dc.citation.volume | 8 | |
dc.citation.issue | 17 | |
dc.citation.spage | 3697 | |
dc.citation.epage | 3700 | |
dc.identifier.wos | 000239655500020 | |
dc.identifier.doi | 10.1021/ol0612760 | |
dc.citation.other | 8(17): 3697-3700 | |
dc.citation.rank | aM21 | |
dc.identifier.pmid | 16898795 | |
dc.type.version | publishedVersion | en |
dc.identifier.scopus | 2-s2.0-33748584333 |