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dc.creatorSredojevic, Dusan N.
dc.creatorTomic, Zoran D.
dc.creatorZarić, Snežana
dc.date.accessioned2018-11-22T00:10:40Z
dc.date.available2018-11-22T00:10:40Z
dc.date.issued2007
dc.identifier.issn1895-1066
dc.identifier.urihttp://cherry.chem.bg.ac.rs/handle/123456789/821
dc.description.abstractIn order to find out whether metal type influences the stacking interactions of phenyl rings in square-planar complexes, geometrical parameters for Cu, Ni, Pd and Pt complexes, with and without chelate rings, were analyzed and compared. By searching the Cambridge Structural Database, 220 structures with Cu complexes, 211 with Ni complexes, 285 with Pd complexes, and 220 with Pt complexes were found. The results show that the chelate ring has a tendency to make the stacking interaction with the phenyl ring independent of metal type in the chelate ring. However, there are some differences among metals for complexes without a chelate ring. There are a number of structures containing Pd and Pt complexes, without chelate rings, that have short carbon-metal distances and parallel orientations of the phenyl ring with respect to the coordination plane. It was found that some of these complexes have a common fragment, CN, as a part of the ligands. This indicates that the CN supports stacking interactions of square planar complexes with the phenyl ring. (C) Versita Warsaw and Springer-Verlag Berlin Heidelberg. All rights reserved.en
dc.publisherVersita, Warsaw 41
dc.rightsopenAccess
dc.sourceCentral European Journal of Chemistry
dc.subjectchelate ringsen
dc.subjectstacking interactionsen
dc.subjecttransition metal complexesen
dc.subjectnon-covalent interactionsen
dc.subjectpi-systemsen
dc.titleInfluence of metal and ligand types on stacking interactions of phenyl rings with square-planar transition metal complexesen
dc.typearticle
dc.rights.licenseBY-NC-ND
dcterms.abstractЗарић, Снежана; Томиц, Зоран Д.; Средојевиц, Дусан Н.;
dc.citation.volume5
dc.citation.issue1
dc.citation.spage20
dc.citation.epage31
dc.identifier.wos000243766100003
dc.identifier.doi10.2478/s11532-006-0068-3
dc.citation.other5(1): 20-31
dc.citation.rankM23
dc.type.versionpublishedVersion
dc.identifier.scopus2-s2.0-33846697649
dc.identifier.rcubKon_1774


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