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dc.creatorSredojevic, Dusan
dc.creatorBogdanović, Goran A.
dc.creatorTomic, Zoran D.
dc.creatorZarić, Snežana
dc.date.accessioned2018-11-22T00:11:20Z
dc.date.available2018-11-22T00:11:20Z
dc.date.issued2007
dc.identifier.issn1466-8033
dc.identifier.urihttp://cherry.chem.bg.ac.rs/handle/123456789/862
dc.description.abstractThe crystal structures of square-planar transition-metal complexes from the Cambridge Structural Database (CSD) with close contacts between planar chelate rings and aryl rings containing six carbon atoms (C-6- aryl) were analyzed. Most of the chelate rings in these structures are fused with aromatic or other pi-delocalized chelate rings. The results show that planar chelate rings can be involved in stacking and CH-pi interactions with organic aryl rings. However, the number of stacking interactions is a few times larger than the number of CH-pi interactions. The analysis also shows that in almost all cases CH-pi interactions are formed only when stacking interactions are prevented by voluminous substituents. Hence, between planar chelate rings and C-6- aryl rings stacking interactions are preferred to CH-pi interactions.en
dc.publisherRoyal Soc Chemistry, Cambridge
dc.rightsrestrictedAccess
dc.sourceCrystEngComm
dc.titleStacking vs. CH-pi interactions between chelate and aryl rings in crystal structures of square-planar transition metal complexesen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractСредојевиц, Дусан; Богдановиц, Горан A.; Томиц, Зоран Д.; Зарић, Снежана;
dc.citation.volume9
dc.citation.issue9
dc.citation.spage793
dc.citation.epage798
dc.identifier.wos000249078700022
dc.identifier.doi10.1039/b704302c
dc.citation.other9(9): 793-798
dc.citation.rankM21
dc.type.versionpublishedVersionen
dc.identifier.scopus2-s2.0-34548232165
dc.identifier.rcubKon_1815


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