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dc.creatorCeković, ž.
dc.creatorSaičić, Radomir
dc.creatorMihailović, M.L.
dc.date.accessioned2018-11-22T00:00:12Z
dc.date.available2018-11-22T00:00:12Z
dc.date.issued1989
dc.identifier.issn0922-6168
dc.identifier.urihttp://cherry.chem.bg.ac.rs/handle/123456789/95
dc.description.abstractIn the lead tetraacetate oxidation of the unsaturated tertiary cyclic alcohols 1a and 1b, and the acyclic alcohol 15a, all possessing a Δ6-olefinic bond (with respect to the hydroxyl group), the α-acetoxylated eight-membered cyclic ethers 6a, 6b and 16a, respectively, were obtained. With these substrates lead tetraaeetate reacts at the double bond and, if at all, only by weak association with the hydroxyl group, so that fragmentation products derived from alkoxy radical intermediates (such as 2) were not formed. The mechanism of this cyclisation reaction is discussed. © 1989, Springer. All rights reserved.en
dc.rightsrestrictedAccess
dc.sourceResearch on Chemical Intermediates
dc.titleThe lead tetraacetate oxidation of Δ6-unsaturated tertiary alcohols. Eight-membered cyclic ether formationen
dc.typearticle
dc.rights.licenseARR
dc.citation.volume11
dc.citation.issue3
dc.citation.spage257
dc.citation.epage270
dc.identifier.doi10.1163/156856789X00375
dc.citation.other11(3): 257-270
dc.identifier.scopus2-s2.0-4243154877
dc.identifier.rcubKon_1172


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