Radical, one-step approach to o-chlorophenyl thioethers from xanthates. A rapid access to vinylsilanes
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Xanthates have been readily converted into o-chlorophenyl thioethers using a one-step procedure conducted under radical conditions. In some selected cases, these aryl thioethers were successfully oxidized to the corresponding sulfoxides and sulfenic acid elimination afforded the corresponding vinylsilanes.
Izvor:Organic Letters, 2008, 10, 16, 3579-3582
- Amer Chemical Soc, Washington