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Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II)
dc.creator | Novaković, Sladjana B. | |
dc.creator | Bogdanović, Goran A. | |
dc.creator | Brčeski, Ilija | |
dc.creator | Leovac, Vukadin M. | |
dc.date.accessioned | 2018-11-22T00:14:56Z | |
dc.date.available | 2018-11-22T00:14:56Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 0108-2701 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/1000 | |
dc.description.abstract | The title compound, [Ni(C20H17N3OP)(N-3)], is the first complex with a semicarbazide-based ligand having a P atom as one of the donors. The influence of the P atom on the deformation of the coordination geometry of the Ni-II ion is evident but less expressed than in the cases of complexes with analogous seleno-and thiosemicarbazide ligands. The torsion angles involving the two bonds formed by the P atom within the six-membered chelate ring have the largest values [C-P-Ni-N = 24.3 (2)degrees and C-C-P-Ni = -24.2 (4)degrees], suggesting that the P atom considerably influences the conformation of the ring. Two types of N-H center dot center dot center dot N hydrogen bond connect the complex units into chains. | en |
dc.publisher | Wiley-Blackwell, Malden | |
dc.relation | info:eu-repo/grantAgreement/MESTD/MPN2006-2010/142028/RS// | |
dc.rights | restrictedAccess | |
dc.source | Acta Crystallographica. Section C: Crystal Structure Communications | |
dc.title | Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II) | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Брчески, Илија; Новаковиц, Сладјана Б.; Леовац, Вукадин М.; Богдановиц, Горан A.; | |
dc.citation.volume | 65 | |
dc.identifier.wos | 000268436500012 | |
dc.identifier.doi | 10.1107/S0108270109021970 | |
dc.citation.other | 65: | |
dc.citation.rank | M23 | |
dc.identifier.pmid | 19578259 | |
dc.type.version | publishedVersion | en |
dc.identifier.scopus | 2-s2.0-67651165477 |
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