RP-TLC Quantitative Retention-Property Relationships Studies of Some Schiff Base Ligands and Their Complexes
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2010
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Prikaz svih podataka o dokumentuApstrakt
Mathematical models which define the effects of molecular properties on the retention and lipophilicity and prediction lipophilicity of some Schiff base ligands, and complexes with copper(II) and nickel(II) were developed. Following molecular descriptors were calculated: molecular volume, surface area, energy of the highest occupied/lowest unoccupied molecular orbital, dipole moment, refractivity, polarizability, hydrophilic-lipophilic balance, and lipophilicity parameters, which are correlated with chromatographically determinated lipophilicity parameters. A multiple linear regression procedure was used to derive the models. High agreement between experimental and predicted values obtained in this validation procedure indicates the good quality of the derived models.
Ključne reči:
Thin-layer chromatography / Quantitative retention-property relationship / Schiff base / Molecular descriptorsIzvor:
Chromatographia, 2010, 72, 5-6, 545-549Izdavač:
- Springer Heidelberg, Heidelberg
Finansiranje / projekti:
- Sinteza, analiza i aktivnost novih organskih polidentatnih liganada i njihovih kompleksa sa d-metalima (RS-MESTD-MPN2006-2010-142062)
DOI: 10.1365/s10337-010-1664-0
ISSN: 0009-5893
WoS: 000281174300023
Scopus: 2-s2.0-77957018731
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Baošić, Rada AU - Radojevic, Ana AU - Tripkovic, Tatjana AU - Aburas, Najat M. AU - Tešić, Živoslav Lj. PY - 2010 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1061 AB - Mathematical models which define the effects of molecular properties on the retention and lipophilicity and prediction lipophilicity of some Schiff base ligands, and complexes with copper(II) and nickel(II) were developed. Following molecular descriptors were calculated: molecular volume, surface area, energy of the highest occupied/lowest unoccupied molecular orbital, dipole moment, refractivity, polarizability, hydrophilic-lipophilic balance, and lipophilicity parameters, which are correlated with chromatographically determinated lipophilicity parameters. A multiple linear regression procedure was used to derive the models. High agreement between experimental and predicted values obtained in this validation procedure indicates the good quality of the derived models. PB - Springer Heidelberg, Heidelberg T2 - Chromatographia T1 - RP-TLC Quantitative Retention-Property Relationships Studies of Some Schiff Base Ligands and Their Complexes VL - 72 IS - 5-6 SP - 545 EP - 549 DO - 10.1365/s10337-010-1664-0 ER -
@article{ author = "Baošić, Rada and Radojevic, Ana and Tripkovic, Tatjana and Aburas, Najat M. and Tešić, Živoslav Lj.", year = "2010", abstract = "Mathematical models which define the effects of molecular properties on the retention and lipophilicity and prediction lipophilicity of some Schiff base ligands, and complexes with copper(II) and nickel(II) were developed. Following molecular descriptors were calculated: molecular volume, surface area, energy of the highest occupied/lowest unoccupied molecular orbital, dipole moment, refractivity, polarizability, hydrophilic-lipophilic balance, and lipophilicity parameters, which are correlated with chromatographically determinated lipophilicity parameters. A multiple linear regression procedure was used to derive the models. High agreement between experimental and predicted values obtained in this validation procedure indicates the good quality of the derived models.", publisher = "Springer Heidelberg, Heidelberg", journal = "Chromatographia", title = "RP-TLC Quantitative Retention-Property Relationships Studies of Some Schiff Base Ligands and Their Complexes", volume = "72", number = "5-6", pages = "545-549", doi = "10.1365/s10337-010-1664-0" }
Baošić, R., Radojevic, A., Tripkovic, T., Aburas, N. M.,& Tešić, Ž. Lj.. (2010). RP-TLC Quantitative Retention-Property Relationships Studies of Some Schiff Base Ligands and Their Complexes. in Chromatographia Springer Heidelberg, Heidelberg., 72(5-6), 545-549. https://doi.org/10.1365/s10337-010-1664-0
Baošić R, Radojevic A, Tripkovic T, Aburas NM, Tešić ŽL. RP-TLC Quantitative Retention-Property Relationships Studies of Some Schiff Base Ligands and Their Complexes. in Chromatographia. 2010;72(5-6):545-549. doi:10.1365/s10337-010-1664-0 .
Baošić, Rada, Radojevic, Ana, Tripkovic, Tatjana, Aburas, Najat M., Tešić, Živoslav Lj., "RP-TLC Quantitative Retention-Property Relationships Studies of Some Schiff Base Ligands and Their Complexes" in Chromatographia, 72, no. 5-6 (2010):545-549, https://doi.org/10.1365/s10337-010-1664-0 . .