Geometries of stacking interactions between phenanthroline ligands in crystal structures of square-planar metal complexes
Abstract
Stacking interactions of phenanthroline square-planar complexes in crystal structures were studied by analyzing data from the Cambridge Structural Database. In most of the crystal structures, two phenanthroline complexes were oriented "head to tail." Phenanthroline complexes show a wide range of overlap geometries in stacking interactions, while short metal-metal distances were not observed. Stacking chains with alternating overlaps were the predominant type of packing in the crystal structures.
Keywords:
Stacking interactions / Cambridge Structural Database / Aromatic / Metal complexesSource:
Journal of Molecular Modeling, 2011, 17, 8, 2083-2092Publisher:
- Springer, New York
Funding / projects:
- Proučavanje odnosa reaktivnosti, nekovalentnih interakcija i strukture molekula i modelovanje hemijskih sistema (RS-MESTD-MPN2006-2010-142037)
- DAAD Foundation
- Humboldt Foundation
DOI: 10.1007/s00894-010-0905-3
ISSN: 1610-2940
PubMed: 21161558
WoS: 000293137800026
Scopus: 2-s2.0-80051781379
Collections
Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Janjić, Goran V. AU - Petrović, Predrag AU - Ninković, Dragan AU - Zarić, Snežana D. PY - 2011 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1181 AB - Stacking interactions of phenanthroline square-planar complexes in crystal structures were studied by analyzing data from the Cambridge Structural Database. In most of the crystal structures, two phenanthroline complexes were oriented "head to tail." Phenanthroline complexes show a wide range of overlap geometries in stacking interactions, while short metal-metal distances were not observed. Stacking chains with alternating overlaps were the predominant type of packing in the crystal structures. PB - Springer, New York T2 - Journal of Molecular Modeling T1 - Geometries of stacking interactions between phenanthroline ligands in crystal structures of square-planar metal complexes VL - 17 IS - 8 SP - 2083 EP - 2092 DO - 10.1007/s00894-010-0905-3 ER -
@article{ author = "Janjić, Goran V. and Petrović, Predrag and Ninković, Dragan and Zarić, Snežana D.", year = "2011", abstract = "Stacking interactions of phenanthroline square-planar complexes in crystal structures were studied by analyzing data from the Cambridge Structural Database. In most of the crystal structures, two phenanthroline complexes were oriented "head to tail." Phenanthroline complexes show a wide range of overlap geometries in stacking interactions, while short metal-metal distances were not observed. Stacking chains with alternating overlaps were the predominant type of packing in the crystal structures.", publisher = "Springer, New York", journal = "Journal of Molecular Modeling", title = "Geometries of stacking interactions between phenanthroline ligands in crystal structures of square-planar metal complexes", volume = "17", number = "8", pages = "2083-2092", doi = "10.1007/s00894-010-0905-3" }
Janjić, G. V., Petrović, P., Ninković, D.,& Zarić, S. D.. (2011). Geometries of stacking interactions between phenanthroline ligands in crystal structures of square-planar metal complexes. in Journal of Molecular Modeling Springer, New York., 17(8), 2083-2092. https://doi.org/10.1007/s00894-010-0905-3
Janjić GV, Petrović P, Ninković D, Zarić SD. Geometries of stacking interactions between phenanthroline ligands in crystal structures of square-planar metal complexes. in Journal of Molecular Modeling. 2011;17(8):2083-2092. doi:10.1007/s00894-010-0905-3 .
Janjić, Goran V., Petrović, Predrag, Ninković, Dragan, Zarić, Snežana D., "Geometries of stacking interactions between phenanthroline ligands in crystal structures of square-planar metal complexes" in Journal of Molecular Modeling, 17, no. 8 (2011):2083-2092, https://doi.org/10.1007/s00894-010-0905-3 . .