Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) Soft Segments
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2016
Authors
Stefanović, Ivan S.Špírková, Milena
Poreba, Rafal
Steinhart, Miloš
Ostojić, Sanja B.
Tešević, Vele
Pergal, Marija V.
Article (Published version)
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Segmented polyurethanes (PURs) were prepared from alpha,omega-dihydroxypoly(propylene oxide)-b-poly-(dimethylsiloxane)-b-poly(propyleneoxide) (PPO-PDMS) as the soft segment and 4,4'-diphenylmethane diisocyanate and 1,4-butanediol as the hard segment, via two-step polyaddition process in solvent mixture. The content of hard segments is in the range from 10 to 60 wt %. The structure and composition of PURs are determined by H-1 NMR, C-13 NMR, and ATR-FTIR spectroscopy. Incorporation of PPO-PDMS leads to improvements in thermal stability. Small- and wide-angle X-ray scattering experiments indicate that synthesized PURs with higher content of hard segments have more developed and distinct phase separated morphologies. Dynamic mechanical thermal analysis shows that copolymers have multiple transitions, characteristic for phase-separated systems. The water contact angle increases while water absorption decreases with increasing content of PPO-PDMS segments. The PURs prepared in this work sho...w good thermal, mechanical features with phase separated morphology and high water resistance that enable their widespread application.
Source:
Industrial and Engineering Chemistry Research, 2016, 55, 14, 3960-3973Publisher:
- Amer Chemical Soc, Washington
Funding / projects:
- Synthesis and characterization of novel functional polymers and polymeric nanocomposites (RS-MESTD-Basic Research (BR or ON)-172062)
- Czech Science Foundation (Grant Agency of the Czech Republic) [1306700S]
Note:
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3618
DOI: 10.1021/acs.iecr.5b04975
ISSN: 0888-5885
WoS: 000374274200010
Scopus: 2-s2.0-84964691145
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Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Stefanović, Ivan S. AU - Špírková, Milena AU - Poreba, Rafal AU - Steinhart, Miloš AU - Ostojić, Sanja B. AU - Tešević, Vele AU - Pergal, Marija V. PY - 2016 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1918 AB - Segmented polyurethanes (PURs) were prepared from alpha,omega-dihydroxypoly(propylene oxide)-b-poly-(dimethylsiloxane)-b-poly(propyleneoxide) (PPO-PDMS) as the soft segment and 4,4'-diphenylmethane diisocyanate and 1,4-butanediol as the hard segment, via two-step polyaddition process in solvent mixture. The content of hard segments is in the range from 10 to 60 wt %. The structure and composition of PURs are determined by H-1 NMR, C-13 NMR, and ATR-FTIR spectroscopy. Incorporation of PPO-PDMS leads to improvements in thermal stability. Small- and wide-angle X-ray scattering experiments indicate that synthesized PURs with higher content of hard segments have more developed and distinct phase separated morphologies. Dynamic mechanical thermal analysis shows that copolymers have multiple transitions, characteristic for phase-separated systems. The water contact angle increases while water absorption decreases with increasing content of PPO-PDMS segments. The PURs prepared in this work show good thermal, mechanical features with phase separated morphology and high water resistance that enable their widespread application. PB - Amer Chemical Soc, Washington T2 - Industrial and Engineering Chemistry Research T1 - Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) Soft Segments VL - 55 IS - 14 SP - 3960 EP - 3973 DO - 10.1021/acs.iecr.5b04975 ER -
@article{ author = "Stefanović, Ivan S. and Špírková, Milena and Poreba, Rafal and Steinhart, Miloš and Ostojić, Sanja B. and Tešević, Vele and Pergal, Marija V.", year = "2016", abstract = "Segmented polyurethanes (PURs) were prepared from alpha,omega-dihydroxypoly(propylene oxide)-b-poly-(dimethylsiloxane)-b-poly(propyleneoxide) (PPO-PDMS) as the soft segment and 4,4'-diphenylmethane diisocyanate and 1,4-butanediol as the hard segment, via two-step polyaddition process in solvent mixture. The content of hard segments is in the range from 10 to 60 wt %. The structure and composition of PURs are determined by H-1 NMR, C-13 NMR, and ATR-FTIR spectroscopy. Incorporation of PPO-PDMS leads to improvements in thermal stability. Small- and wide-angle X-ray scattering experiments indicate that synthesized PURs with higher content of hard segments have more developed and distinct phase separated morphologies. Dynamic mechanical thermal analysis shows that copolymers have multiple transitions, characteristic for phase-separated systems. The water contact angle increases while water absorption decreases with increasing content of PPO-PDMS segments. The PURs prepared in this work show good thermal, mechanical features with phase separated morphology and high water resistance that enable their widespread application.", publisher = "Amer Chemical Soc, Washington", journal = "Industrial and Engineering Chemistry Research", title = "Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) Soft Segments", volume = "55", number = "14", pages = "3960-3973", doi = "10.1021/acs.iecr.5b04975" }
Stefanović, I. S., Špírková, M., Poreba, R., Steinhart, M., Ostojić, S. B., Tešević, V.,& Pergal, M. V.. (2016). Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) Soft Segments. in Industrial and Engineering Chemistry Research Amer Chemical Soc, Washington., 55(14), 3960-3973. https://doi.org/10.1021/acs.iecr.5b04975
Stefanović IS, Špírková M, Poreba R, Steinhart M, Ostojić SB, Tešević V, Pergal MV. Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) Soft Segments. in Industrial and Engineering Chemistry Research. 2016;55(14):3960-3973. doi:10.1021/acs.iecr.5b04975 .
Stefanović, Ivan S., Špírková, Milena, Poreba, Rafal, Steinhart, Miloš, Ostojić, Sanja B., Tešević, Vele, Pergal, Marija V., "Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) Soft Segments" in Industrial and Engineering Chemistry Research, 55, no. 14 (2016):3960-3973, https://doi.org/10.1021/acs.iecr.5b04975 . .