Identification and quantification of phenolic compounds in berry skin, pulp, and seeds in 13 grapevine varieties grown in Serbia
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2016
Authors
Sredojević, Milica![](/themes/MirageCherry/images/orcid.png)
Dabić Zagorac, Dragana
![](/themes/MirageCherry/images/orcid.png)
Davidovic, Sonja M.
Todić, Slavica
Bešlić, Zoran
Gašić, Uroš M.
![](/themes/MirageCherry/images/orcid.png)
Tešić, Živoslav Lj.
![](/themes/MirageCherry/images/orcid.png)
Natić, Maja
![](/themes/MirageCherry/images/orcid.png)
Article (Published version)
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Phenolic profile of 13 grapevine varieties was determined, with respect to three different parts of berries: skin, seed and pulp. Identification and quantification of the phenols was done using ultra -high performance liquid chromatography (UHPLC) coupled with a diode array detector and a triple-quadrupole mass spectrometer. The most abundant phenols in grape seeds were found to be flavan-3-ols, most of which are gallocatechin gallate and catechin. The skins were characterized mostly by flavonols, i.e. quercetin and myricetin. Characterization of anthocyanins in the berry skin by UHPLC coupled with Linear Trap Quadrupole and OrbiTrap mass analyzer revealed a total of twenty derivatives of malvidin, delphinidin, petunidin, cyanidin, and peonidin. To the extent of our knowledge this is the first work that shows the presence of malvidin 3,5-0-dihexoside in the berry skin of 'Merlof, 'Cabernet Franc', 'Shiraz' 'Sangiovese', 'Pinot Noir' and 'Prokupac', untypical for Vitis vinifera Linneo s...pecies. (C) 2016 Elsevier Ltd. All rights reserved.
Keywords:
Grape / Phenolic profile / Anthocyanins / Antioxidant activity / LC/MS / PCASource:
Food Chemistry, 2016, 211, 243-252Publisher:
- Elsevier Sci Ltd, Oxford
Funding / projects:
- Structure-properties relationships of natural and synthetic molecules and their metal complexes (RS-MESTD-Basic Research (BR or ON)-172017)
- Studying climate change and its influence on environment: impacts, adaptation and mitigation (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43007)
Note:
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3529
DOI: 10.1016/j.foodchem.2016.05.051
ISSN: 0308-8146
PubMed: 27283628
WoS: 000377543500029
Scopus: 2-s2.0-84973358467
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Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Sredojević, Milica AU - Dabić Zagorac, Dragana AU - Davidovic, Sonja M. AU - Todić, Slavica AU - Bešlić, Zoran AU - Gašić, Uroš M. AU - Tešić, Živoslav Lj. AU - Natić, Maja PY - 2016 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2260 AB - Phenolic profile of 13 grapevine varieties was determined, with respect to three different parts of berries: skin, seed and pulp. Identification and quantification of the phenols was done using ultra -high performance liquid chromatography (UHPLC) coupled with a diode array detector and a triple-quadrupole mass spectrometer. The most abundant phenols in grape seeds were found to be flavan-3-ols, most of which are gallocatechin gallate and catechin. The skins were characterized mostly by flavonols, i.e. quercetin and myricetin. Characterization of anthocyanins in the berry skin by UHPLC coupled with Linear Trap Quadrupole and OrbiTrap mass analyzer revealed a total of twenty derivatives of malvidin, delphinidin, petunidin, cyanidin, and peonidin. To the extent of our knowledge this is the first work that shows the presence of malvidin 3,5-0-dihexoside in the berry skin of 'Merlof, 'Cabernet Franc', 'Shiraz' 'Sangiovese', 'Pinot Noir' and 'Prokupac', untypical for Vitis vinifera Linneo species. (C) 2016 Elsevier Ltd. All rights reserved. PB - Elsevier Sci Ltd, Oxford T2 - Food Chemistry T1 - Identification and quantification of phenolic compounds in berry skin, pulp, and seeds in 13 grapevine varieties grown in Serbia VL - 211 SP - 243 EP - 252 DO - 10.1016/j.foodchem.2016.05.051 ER -
@article{ author = "Sredojević, Milica and Dabić Zagorac, Dragana and Davidovic, Sonja M. and Todić, Slavica and Bešlić, Zoran and Gašić, Uroš M. and Tešić, Živoslav Lj. and Natić, Maja", year = "2016", abstract = "Phenolic profile of 13 grapevine varieties was determined, with respect to three different parts of berries: skin, seed and pulp. Identification and quantification of the phenols was done using ultra -high performance liquid chromatography (UHPLC) coupled with a diode array detector and a triple-quadrupole mass spectrometer. The most abundant phenols in grape seeds were found to be flavan-3-ols, most of which are gallocatechin gallate and catechin. The skins were characterized mostly by flavonols, i.e. quercetin and myricetin. Characterization of anthocyanins in the berry skin by UHPLC coupled with Linear Trap Quadrupole and OrbiTrap mass analyzer revealed a total of twenty derivatives of malvidin, delphinidin, petunidin, cyanidin, and peonidin. To the extent of our knowledge this is the first work that shows the presence of malvidin 3,5-0-dihexoside in the berry skin of 'Merlof, 'Cabernet Franc', 'Shiraz' 'Sangiovese', 'Pinot Noir' and 'Prokupac', untypical for Vitis vinifera Linneo species. (C) 2016 Elsevier Ltd. All rights reserved.", publisher = "Elsevier Sci Ltd, Oxford", journal = "Food Chemistry", title = "Identification and quantification of phenolic compounds in berry skin, pulp, and seeds in 13 grapevine varieties grown in Serbia", volume = "211", pages = "243-252", doi = "10.1016/j.foodchem.2016.05.051" }
Sredojević, M., Dabić Zagorac, D., Davidovic, S. M., Todić, S., Bešlić, Z., Gašić, U. M., Tešić, Ž. Lj.,& Natić, M.. (2016). Identification and quantification of phenolic compounds in berry skin, pulp, and seeds in 13 grapevine varieties grown in Serbia. in Food Chemistry Elsevier Sci Ltd, Oxford., 211, 243-252. https://doi.org/10.1016/j.foodchem.2016.05.051
Sredojević M, Dabić Zagorac D, Davidovic SM, Todić S, Bešlić Z, Gašić UM, Tešić ŽL, Natić M. Identification and quantification of phenolic compounds in berry skin, pulp, and seeds in 13 grapevine varieties grown in Serbia. in Food Chemistry. 2016;211:243-252. doi:10.1016/j.foodchem.2016.05.051 .
Sredojević, Milica, Dabić Zagorac, Dragana, Davidovic, Sonja M., Todić, Slavica, Bešlić, Zoran, Gašić, Uroš M., Tešić, Živoslav Lj., Natić, Maja, "Identification and quantification of phenolic compounds in berry skin, pulp, and seeds in 13 grapevine varieties grown in Serbia" in Food Chemistry, 211 (2016):243-252, https://doi.org/10.1016/j.foodchem.2016.05.051 . .