Amperometric quantification of the pesticide ziram at boron doped diamond electrodes using flow injection analysis
Abstract
In this paper sensitive and selective quantification of the pesticide ziram exploiting its oxidation at a boron doped diamond (BDD) electrode is evaluated. The voltammetric behavior of the pesticide shows in acidic media three well-defined oxidation peaks. For quantification an analytical procedure based on flow injection analysis has been developed. Under optimized experimental conditions a linear dynamic range from 10 to 1000 nM was obtained. The limit of detection (LOD) was estimated to be 2.7 nM. Aftere valuation of effects from possible interferences, the proposed procedure was successfully applied to real samples. (C) 2016 Elsevier B.V. All rights reserved.
Keywords:
Boron doped diamond / Sensitivity / Dimethyl-dithiocarbamate / Cuman LSource:
Sensors and Actuators B: Chemical, 2016, 233, 144-147Publisher:
- Elsevier Science Sa, Lausanne
Funding / projects:
- Application of advanced oxidation processes and nanostructured oxide materials for the removal of pollutants from the environment, development and optimisation of instrumental techniques for efficiency monitoring (RS-MESTD-Basic Research (BR or ON)-172030)
- JoinEU-SEE-Penta Erasmus Mundus scholarship
DOI: 10.1016/j.snb.2016.04.069
ISSN: 0925-4005
WoS: 000386830200002
Scopus: 2-s2.0-84963960242
Collections
Institution/Community
Inovacioni centar / Innovation CentreTY - JOUR AU - Stanković, Dalibor AU - Kalcherb, Kurt PY - 2016 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2341 AB - In this paper sensitive and selective quantification of the pesticide ziram exploiting its oxidation at a boron doped diamond (BDD) electrode is evaluated. The voltammetric behavior of the pesticide shows in acidic media three well-defined oxidation peaks. For quantification an analytical procedure based on flow injection analysis has been developed. Under optimized experimental conditions a linear dynamic range from 10 to 1000 nM was obtained. The limit of detection (LOD) was estimated to be 2.7 nM. Aftere valuation of effects from possible interferences, the proposed procedure was successfully applied to real samples. (C) 2016 Elsevier B.V. All rights reserved. PB - Elsevier Science Sa, Lausanne T2 - Sensors and Actuators B: Chemical T1 - Amperometric quantification of the pesticide ziram at boron doped diamond electrodes using flow injection analysis VL - 233 SP - 144 EP - 147 DO - 10.1016/j.snb.2016.04.069 ER -
@article{ author = "Stanković, Dalibor and Kalcherb, Kurt", year = "2016", abstract = "In this paper sensitive and selective quantification of the pesticide ziram exploiting its oxidation at a boron doped diamond (BDD) electrode is evaluated. The voltammetric behavior of the pesticide shows in acidic media three well-defined oxidation peaks. For quantification an analytical procedure based on flow injection analysis has been developed. Under optimized experimental conditions a linear dynamic range from 10 to 1000 nM was obtained. The limit of detection (LOD) was estimated to be 2.7 nM. Aftere valuation of effects from possible interferences, the proposed procedure was successfully applied to real samples. (C) 2016 Elsevier B.V. All rights reserved.", publisher = "Elsevier Science Sa, Lausanne", journal = "Sensors and Actuators B: Chemical", title = "Amperometric quantification of the pesticide ziram at boron doped diamond electrodes using flow injection analysis", volume = "233", pages = "144-147", doi = "10.1016/j.snb.2016.04.069" }
Stanković, D.,& Kalcherb, K.. (2016). Amperometric quantification of the pesticide ziram at boron doped diamond electrodes using flow injection analysis. in Sensors and Actuators B: Chemical Elsevier Science Sa, Lausanne., 233, 144-147. https://doi.org/10.1016/j.snb.2016.04.069
Stanković D, Kalcherb K. Amperometric quantification of the pesticide ziram at boron doped diamond electrodes using flow injection analysis. in Sensors and Actuators B: Chemical. 2016;233:144-147. doi:10.1016/j.snb.2016.04.069 .
Stanković, Dalibor, Kalcherb, Kurt, "Amperometric quantification of the pesticide ziram at boron doped diamond electrodes using flow injection analysis" in Sensors and Actuators B: Chemical, 233 (2016):144-147, https://doi.org/10.1016/j.snb.2016.04.069 . .