Cyclic voltammetry and UV/Vis spectroscopy in combination with multivariate data analysis for the assessment of authenticity of poplar type propolis
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2017
Authors
Ristivojević, PetarTrifković, Jelena
Stanković, Dalibor
Radoičić, Aleksandra
Manojlović, Dragan D.
Milojković-Opsenica, Dušanka
Article (Published version)
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Propolis, as a beneficial natural product, has found application in the food and pharmaceutical industries as a food preservative, active packaging material as well as a main component of propolis containing products. Quality control of propolis has thus gained in importance. We used simple, fast, and low-cost techniques such as UV/Vis spectrophotometry and cyclic voltammetry applied in combination with principal component analysis to confirm the presence of two botanical sub-types of propolis. Cyclic voltammetry, as a green, sensitive, and convenient technique suitable for investigation of chemical profile, together with multivariate chemometrics technique, was used for the first time for characterization and classification of propolis. UV/Vis spectroscopy was applied in two aspects, absorption at certain wavelength for the quantitative determination of analytes, i.e. determination of quality control parameters, and spectral profiles, for the confirmation of the existence of two botan...ically different poplar types. All investigated Serbian propolis samples were characterized with specific chemical patterns and were classified in two main botanical varieties, so-called orange and blue. The results confirmed that the applied methods have a potential to be used for the discrimination of complex natural products such as propolis.
Keywords:
orange and blue propolis / cyclic voltammetry / UV/Vis spectrometry / principal component analysis / quality control parametersSource:
Journal of Apicultural Research, 2017, 56, 5, 559-568Publisher:
- Taylor & Francis Ltd, Abingdon
Funding / projects:
- Structure-properties relationships of natural and synthetic molecules and their metal complexes (RS-MESTD-Basic Research (BR or ON)-172017)
- Application of advanced oxidation processes and nanostructured oxide materials for the removal of pollutants from the environment, development and optimisation of instrumental techniques for efficiency monitoring (RS-MESTD-Basic Research (BR or ON)-172030)
Note:
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3032
DOI: 10.1080/00218839.2017.1357217
ISSN: 0021-8839
WoS: 000413469200008
Scopus: 2-s2.0-85030457051
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Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Ristivojević, Petar AU - Trifković, Jelena AU - Stanković, Dalibor AU - Radoičić, Aleksandra AU - Manojlović, Dragan D. AU - Milojković-Opsenica, Dušanka PY - 2017 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2545 AB - Propolis, as a beneficial natural product, has found application in the food and pharmaceutical industries as a food preservative, active packaging material as well as a main component of propolis containing products. Quality control of propolis has thus gained in importance. We used simple, fast, and low-cost techniques such as UV/Vis spectrophotometry and cyclic voltammetry applied in combination with principal component analysis to confirm the presence of two botanical sub-types of propolis. Cyclic voltammetry, as a green, sensitive, and convenient technique suitable for investigation of chemical profile, together with multivariate chemometrics technique, was used for the first time for characterization and classification of propolis. UV/Vis spectroscopy was applied in two aspects, absorption at certain wavelength for the quantitative determination of analytes, i.e. determination of quality control parameters, and spectral profiles, for the confirmation of the existence of two botanically different poplar types. All investigated Serbian propolis samples were characterized with specific chemical patterns and were classified in two main botanical varieties, so-called orange and blue. The results confirmed that the applied methods have a potential to be used for the discrimination of complex natural products such as propolis. PB - Taylor & Francis Ltd, Abingdon T2 - Journal of Apicultural Research T1 - Cyclic voltammetry and UV/Vis spectroscopy in combination with multivariate data analysis for the assessment of authenticity of poplar type propolis VL - 56 IS - 5 SP - 559 EP - 568 DO - 10.1080/00218839.2017.1357217 ER -
@article{ author = "Ristivojević, Petar and Trifković, Jelena and Stanković, Dalibor and Radoičić, Aleksandra and Manojlović, Dragan D. and Milojković-Opsenica, Dušanka", year = "2017", abstract = "Propolis, as a beneficial natural product, has found application in the food and pharmaceutical industries as a food preservative, active packaging material as well as a main component of propolis containing products. Quality control of propolis has thus gained in importance. We used simple, fast, and low-cost techniques such as UV/Vis spectrophotometry and cyclic voltammetry applied in combination with principal component analysis to confirm the presence of two botanical sub-types of propolis. Cyclic voltammetry, as a green, sensitive, and convenient technique suitable for investigation of chemical profile, together with multivariate chemometrics technique, was used for the first time for characterization and classification of propolis. UV/Vis spectroscopy was applied in two aspects, absorption at certain wavelength for the quantitative determination of analytes, i.e. determination of quality control parameters, and spectral profiles, for the confirmation of the existence of two botanically different poplar types. All investigated Serbian propolis samples were characterized with specific chemical patterns and were classified in two main botanical varieties, so-called orange and blue. The results confirmed that the applied methods have a potential to be used for the discrimination of complex natural products such as propolis.", publisher = "Taylor & Francis Ltd, Abingdon", journal = "Journal of Apicultural Research", title = "Cyclic voltammetry and UV/Vis spectroscopy in combination with multivariate data analysis for the assessment of authenticity of poplar type propolis", volume = "56", number = "5", pages = "559-568", doi = "10.1080/00218839.2017.1357217" }
Ristivojević, P., Trifković, J., Stanković, D., Radoičić, A., Manojlović, D. D.,& Milojković-Opsenica, D.. (2017). Cyclic voltammetry and UV/Vis spectroscopy in combination with multivariate data analysis for the assessment of authenticity of poplar type propolis. in Journal of Apicultural Research Taylor & Francis Ltd, Abingdon., 56(5), 559-568. https://doi.org/10.1080/00218839.2017.1357217
Ristivojević P, Trifković J, Stanković D, Radoičić A, Manojlović DD, Milojković-Opsenica D. Cyclic voltammetry and UV/Vis spectroscopy in combination with multivariate data analysis for the assessment of authenticity of poplar type propolis. in Journal of Apicultural Research. 2017;56(5):559-568. doi:10.1080/00218839.2017.1357217 .
Ristivojević, Petar, Trifković, Jelena, Stanković, Dalibor, Radoičić, Aleksandra, Manojlović, Dragan D., Milojković-Opsenica, Dušanka, "Cyclic voltammetry and UV/Vis spectroscopy in combination with multivariate data analysis for the assessment of authenticity of poplar type propolis" in Journal of Apicultural Research, 56, no. 5 (2017):559-568, https://doi.org/10.1080/00218839.2017.1357217 . .