The anisotropic pi-effect of the nitro group in ammine-nitro cobalt(III) complexes
Abstract
The analysis of crystal structures of the series of ammine-nitro cobalt(III) complexes has shown that Co-NO2 bond lengths can be successfully rationalized on the basis of the anisotropic pi-effect of nitro groups. This effect governs both the orientation of the nitro group and the Co-NO2 length, and explains the irregularities in the increase of the latter with the increasing number of NO2 groups present in the coordination sphere. (C) 1997 Elsevier Science Ltd.
Keywords:
anisotropic pi-effect / ammine-nitro complexes / cobalt(III) complexes / metal-ligand bond / pi-bonding / stereochemistrySource:
Polyhedron, 1997, 16, 20, 3565-3569Publisher:
- Pergamon-Elsevier Science Ltd, Oxford
DOI: 10.1016/S0277-5387(97)00112-5
ISSN: 0277-5387
WoS: A1997XQ92400014
Scopus: 2-s2.0-0039054225
Collections
Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Zarić, Snežana D. AU - Niketic, SR PY - 1997 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2594 AB - The analysis of crystal structures of the series of ammine-nitro cobalt(III) complexes has shown that Co-NO2 bond lengths can be successfully rationalized on the basis of the anisotropic pi-effect of nitro groups. This effect governs both the orientation of the nitro group and the Co-NO2 length, and explains the irregularities in the increase of the latter with the increasing number of NO2 groups present in the coordination sphere. (C) 1997 Elsevier Science Ltd. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Polyhedron T1 - The anisotropic pi-effect of the nitro group in ammine-nitro cobalt(III) complexes VL - 16 IS - 20 SP - 3565 EP - 3569 DO - 10.1016/S0277-5387(97)00112-5 ER -
@article{ author = "Zarić, Snežana D. and Niketic, SR", year = "1997", abstract = "The analysis of crystal structures of the series of ammine-nitro cobalt(III) complexes has shown that Co-NO2 bond lengths can be successfully rationalized on the basis of the anisotropic pi-effect of nitro groups. This effect governs both the orientation of the nitro group and the Co-NO2 length, and explains the irregularities in the increase of the latter with the increasing number of NO2 groups present in the coordination sphere. (C) 1997 Elsevier Science Ltd.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Polyhedron", title = "The anisotropic pi-effect of the nitro group in ammine-nitro cobalt(III) complexes", volume = "16", number = "20", pages = "3565-3569", doi = "10.1016/S0277-5387(97)00112-5" }
Zarić, S. D.,& Niketic, S.. (1997). The anisotropic pi-effect of the nitro group in ammine-nitro cobalt(III) complexes. in Polyhedron Pergamon-Elsevier Science Ltd, Oxford., 16(20), 3565-3569. https://doi.org/10.1016/S0277-5387(97)00112-5
Zarić SD, Niketic S. The anisotropic pi-effect of the nitro group in ammine-nitro cobalt(III) complexes. in Polyhedron. 1997;16(20):3565-3569. doi:10.1016/S0277-5387(97)00112-5 .
Zarić, Snežana D., Niketic, SR, "The anisotropic pi-effect of the nitro group in ammine-nitro cobalt(III) complexes" in Polyhedron, 16, no. 20 (1997):3565-3569, https://doi.org/10.1016/S0277-5387(97)00112-5 . .